СOORDINATION COMPOUNDS OF SOME D-METALS OF TETRATHIOARSENATES (V) WITH ORTO-PHENYLENEDIAMINE
Journal Title: INTERNATIONAL ACADEMY JOURNAL "Web of Scholar" - Year 2018, Vol 2, Issue 1
Abstract
Synthesized and studied coordination compounds tetrathiarsenates(V)d-metals, iron(II) and cobalt(II) with ortho-phenylenediamine by the general formula: [M(C6H8N2)3]3(AsS4)2. Synthesized compounds are mildly crystalline substances of different colors. Their composition and structure are established by IR spectral, elemental, X-ray and thermographic analysis methods. It was shown that the bond between the ligand and the complex-forming agent obtained through the nitrogen atoms and tetrotriarsenate-ion is in the outer sphere of the complex.
Authors and Affiliations
Izolda Didbaridze, Nodar Lekishvili, Lagi Gvetadze, Nestan Bregadze
Keywords
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