4-Aryl-2, 6-di(pyren-1-yl)pyridines: A facile procedure for synthesis and studying of fluorescence properties

Journal Title: Eurasian Chemical Communications - Year 2019, Vol 1, Issue 0

Abstract

Pyrene and its derivatives exhibit thermal stability, high extinction coefficients, excimer formation, high photoluminescence, long fluorescence lifetime, fluorophoric properties and enhanced charge carrier mobility which make them find applications in optoelectronic area and are useful as large planar synthetic building blocks in supramolecular chemistry. One of the approaches to overcome this downside is the introduction of bulky aryl/alkyl substituents or incorporation heteroatoms into the π-extended conjugated system of pyrene. In this work, Some new derivatives of 4-Aryl-2, 6-di(pyren-1-yl)pyridines have been synthesized through one-pot reaction and were formed with cyclization of Arylaldehydes, 1-acetylpyrene and ammonium acetate in acetic acid. The products were confirmed by FT-IR, Mass, 1H-NMR, 13C-NMR and elemental analysis. These new compounds were subsequently studied for their fluorescence properties.

Authors and Affiliations

Mohammad Reza Asaadi, Hosein Behmadi, Abdolhossein Massoudi, Mohammad Shaker

Keywords

Related Articles

The effect of magnetic field on the magnetic property of Agar/Fe3O4 nanocomposite

Agar/Fe3O4 nanocomposites were synthesized in the presence of an external magnetic field (~ 0.4 Tesla) and their characteristics were compared with the samples synthesized without considering the external magnetic field....

The mechanism of proton transfer and tautomerism in barbituric acid: A theoretical study

Intermolecular proton transfer in barbituric acid (BA) both in the gas phase and in the presence of water molecule was investigated using the B3LYP method with aug-cc-pVDZ basis set. The overall process involves keto-eno...

Informatics aided QSRR study of retention index of some volatile compounds

In the present work, an artificial neural network (ANN) model was used to study the quantitative structure retention relationship (QSRR) of retention index (RI) of some volatile compounds in natural cocoa and conched cho...

Nanomagnetic organic-inorganic hybrid (CuFe2O4@Si-Imid-PMo): an efficient green catalyst for the synthesis of 2,4,5-trisubstituted imidazoles

In this research, a new magnetic nanocatalyst CuFe2O4@Si-Imid-PMo containing acidic ionic liquid based on imidazolium cation and phosphomolybdic acid anion immobilized on CuFe2O4@SiO2 magnetic nanoparticles was prepared...

Photosensitization of coronene–purine hybrids for photodynamic therapy

Photosensitization properties of coronene-purine (Cor-P) hybrids for photodynamic therapy (PDT) have been investigated in this work. Eight hybrid Cor-P models have been designed by the additional of adenine (A) and guani...

Download PDF file
  • EP ID EP658102
  • DOI 10.33945/SAMI/ECC.2019.3.7
  • Views 171
  • Downloads 0

How To Cite

Mohammad Reza Asaadi, Hosein Behmadi, Abdolhossein Massoudi, Mohammad Shaker (2019). 4-Aryl-2, 6-di(pyren-1-yl)pyridines: A facile procedure for synthesis and studying of fluorescence properties. Eurasian Chemical Communications, 1(0), 302-309. https://europub.co.uk/articles/-A-658102