A FACILE SYNTHESIS OF PALLADIUM CONTAINING METALLODENDRIMER BASED ON DIAZINE AND ITS APPLICATION AS A CATALYST.
Journal Title: International Journal of Advanced Research (IJAR) - Year 2019, Vol 7, Issue 3
Abstract
A palladium containing metallodendrimer has been directly prepared by the reaction of 2,4,6-Triaminopyrimidine (Diazine) with 4-methyl benzoyl chloride using (Ph3P)2PdCl2 in DMF at 70 oC in good yields. The compound was characterized with IR, NMR, Mass and other spectroscopic methods while SEM andEDX showed the surface morphology and the presence of Palladium chloride of the compound. TG and DSC exhibited the good thermal stability of themetallodendrimer. The compound was found to be an effective homogeneous catalyst for the C-C cross-coupling reaction such as Heck and Sonogashira.
Authors and Affiliations
Md. Sayedul Islam, Md. Wahab Khan.
Keywords
Related Articles
- EP ID EP544970
- DOI 10.21474/IJAR01/8758
- Views 56
- Downloads 0
VISCOELASTIC PROPERTIES OF HARD AND SOFT DENTURE BASE RELINE MATERIALS
Background: Reline materials are integral part in management of patients wearing removal complete dentures. Objectives: The objective of this study was to assess and compare the viscoelastic properties of the permanent h...
BILATERAL BREAST HYPERTROPHY (GIGANTOMASTIA).
Gigantomastia is a rare condition characterized by excessive breast growth. It may occur spontaneously, during puberty or pregnancy, or while taking certain medications.There is no universally accepted definition of giga...
BACTERIAL CONTAMINATION OF SOME VEGETABLES SOLD IN MAJOR MARKETS IN ADOEKITI, NIGERIA.
Consumption of vegetables contaminated with pathogens is a common source of infections. This study investigated bacterial contamination of vegetables sold in major markets in Ado-Ekiti, Nigeria. Sixty samples comprising...
UTILIZATION OF UNZASEDA SHORT COURSES BY PURSUERS.
Short course provisioning is one of the most dynamic features of the emerging education and training system in the world of late. This kind of provisioning is particularly associated with ?just in time?, and ?just enough...
GOND FESTIVAL; THE RITUAL THEATRE.
Gonds of Adilabad, have their ways of expression and living, they have their psychological and spiritual reasons behind why they keep doing what they do. They never looked for a reason to escape or discard what they have...