Analysis of C-H…..F and O-H…..N Intermolecular Interactions Involving Fluorine in A New Mixed Composite Material 5- Fluoro salicylaldehyde –Aniline
Journal Title: UNKNOWN - Year 2015, Vol 4, Issue 1
Abstract
We synthesized a new composite material containing 5-Fluoro salicylaldehyde with Aniline in CCl4 medium. A detailed packing analysis has been undertaken to delineate the role of C-H….F interactions amid other hetroatom interactions. The composite material have been characterized by elemental analyses, Spectroscopic studies (IR, multinuclear NMR) and Physico-chemical behavioural studies. The complex structure is calculated by the spectral analyses as non-centro symmetric, bent, complex in nature, containing five interacting nuclei A BB’ MM’ system. The composite material was stabilized by a variety of hydrogen bonding interactions (i.e) O-H…..N and C-H……F. Furthermore, packing analyses reveal that C-H……F interactions can manifest even in the presence of a large number of hetroatom interactions. To reinforce the ideas investigated and to reveal the validity of the proposed models, experimental results are discussed with the outputs through the Software MATLAB7.0.
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