Application of N-4,4'-azodianiline(ferrocenyl Schiff base) for electrocatalytic determination of atenolol on modified carbon paste electrode
Journal Title: Iranian Chemical Communication - Year 2015, Vol 3, Issue 1
Abstract
A carbon-paste electrode (CPE) chemically modified with the N-4,4'-azodianiline(ferrocenyl Schiff base) complex and multi wall carbon nanotubes (ADAFCNTE) was used as a highly sensitive electrochemical sensor for determination of trace amounts of atenolol. The oxidation peak potentials in cyclic voltammogram of ADAFCNTE occurred around 550 mV vs Ag/AgCl (at pH 6.0) while this peak potential at the carbon paste electrode appeared around 800 mV at the same scan rate of 10 mV s−1. The kinetic parameters such as electron transfer coefficient, α, and rate constant for chemical reaction between atenolol and redox sites in modified electrode were 0.41 and 2.8×102 cm3 mol-1 s-1, respectively. The catalytic peak current was linearly dependent on atenolol concentration in the range of 0.1-57.0 µmol L-1 with a detection limit of 0.08 µmol L-1. Finally, the sensor was examined as a selective, simple and precise new electrochemical sensor for the determination of atenolol in urine samples, with satisfactory results.
Authors and Affiliations
Masoumeh Taei, Foroozan Hasanpour, Marjan Shavakhi
Keywords
Related Articles
- EP ID EP258545
- DOI -
- Views 92
- Downloads 0
Magnetic nanoparticle immobilized N-propylsulfamic acid: The efficient, green and reusable nanocatalyst for the synthesis of substituted coumarins
N-Propylsulfamic acid supported onto magnetic Fe3O4 nanoparticles (MNPs-PSA) was investigated as an efficient and magnetically recoverable catalyst for the one-pot synthesis of substituted coumarins from the reaction of...
Fe2V4O13 assisted hetero-Fenton mineralization of methyl orange under UV-A light irradiation
Fe2V4O13 is prepared and characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), UV-diffuse reflectance spectroscopy (UV-DRS), high resolution scanning electron microscopy (HR-SEM) using energy disp...
One-pot three-component synthesis of dialkyl 3-(alkylamino)-1-aryl-1H-pyrazole-4,5-dicarboxylates using α-Fe2O3 nanoparticles and phenylisocyanate in solvent-free conditions
This work described a simple and efficient synthesis of dialkyl 3-(alkylamino)-1-aryl-1H-pyrazole-4,5-dicarboxylates via a three component reaction between arylhydrazine, alkylisocyanid and dialkylacetylenedicarboxylates...
pKa predictions of some aniline derivatives by ab initio calculations
: In this work, different levels of theory containing HF, B3LYP, and MP2 with different basis sets such as 6-31G, 6-31G*, 6-311G, 6-311+G, 6-31+G*, 6-31+G are used to predict relative acidity constants of some aniline de...
Fabrication and Characterization of Nanostructured TiO2 and Turmeric Spent Incorporated Polystyrene Hybrid Nano Composites
A series of polystyrene hybrid nanocomposites have been fabricated with varying amounts of TiO2 viz., 0, 0.5 and 1 % w/w along with 3% TS by in-situ polymerization method. The influence of surface modified TiO2 nanoparti...