Betainy jako akceptory protonu
Journal Title: Wiadomości Chemiczne - Year 2017, Vol 71, Issue 7
Abstract
Ammonium alkanoates (ammonioalkanocarboxylates) are zwitterions (or inner salts, or betaines), because they possess formally charged ammonium and carboxylate groups separated by one or more sp3 carbon atoms. The chemistry of betaines has become a subject of particular interest due to their applications in biological research, especially with regard to their important role in aminoacid synthesis as methyl transfer agents. The crystals of many betaine complexes display interesting physical properties, exhibiting phase transitions with ferroelectric, antiferroelctric and ferroelastic behavior. Betaines containing a hydrophobic chain in the range of 8–20 carbon atoms show the unique properties characteristic for amphoteric surfactants and their current industrial application is in toiletries and personal care products. The conformational structure of zwitterionic molecules depends on several factors. The electrostatic attraction between two charged groups depends strongly on arm flexibility (energy differences between rotational trans and gauche isomers), bulkiness and hydration of charged groups preventing their close approach, solvent and arm electrical properties which control electrostatic attraction between two opposite charged groups, and polarization of solvent around the molecule caused by the dielectric discontinuity between solvent and solute interior (image charge effect). Electrostatic interaction is the common determinant and probably the most important element in structure-reactivity correlation in organic and biological systems. On the other hand, organic compounds are thought to be pure even though they may be a mixture of conformational isomers. This is because the isomers covert rapidly with each other at room temperature and their individual reactivates are little known. Occasionally the conformers may be stabilized in the crystallographic matrixes of polymorphic structures. This article describes structures of seven groups of aliphatic, aromatic and alicyclic betaines and numbers of their new hydrogen-bonded complexes with mineral and organic acids.
Authors and Affiliations
Zofia Dega-Szafran, Mirosław Szafran
Keywords
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