Determination of Solute-Solute and Solute-Solvent Interactions of 4-Oxo-2-Thioxo Pyrimidine Carbonitriles in 60% Aqueous DMSO At 303.15 K
Journal Title: Bulletin of Pure and Applied Sciences Sec. C – Chemistry - Year 2018, Vol 37, Issue 2
Abstract
Solute-solute and solute-solvent interactions of 4-oxo-2-thioxo pyrimidine carbonitriles have been analysed by densitometric and viscometric study in 60% aqueous dimethyl sulphoxide (DMSO) at 303.15 K. From the experimental data the related parameters such as apparent molar volume, limiting apparent molar volume, semi-empirical parameter, Falkenhagen coefficient and Jones Dole coefficient were evaluated. Such parameter gives identification of molecular interactions.
Authors and Affiliations
Manoj R. Gaware
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