Direct Electrochemical Synthesis of Organobismuth Compounds and their coordination compounds
Journal Title: International Journal of engineering Research and Applications - Year 2017, Vol 7, Issue 10
Abstract
Organobismuth and organobismuth halides have been synthesized by electrolyzing the solutions of alkyl/aryl halides (bromoethane, 1-bromopropane, 1-chlorobutane and chlorobenzene ) in acetonitrile at sacrificial bismuth anode. These organobismuth halides do not form coordination compounds when refluxed with ligands such as 1,10-phenanthroline and 2,2'-bipyridyl. However, coordination compounds of these organobismuth compounds have been synthesized by electrolyzing the solution of the above substrate in the presence of ligands in acetonitrile at sacrificial bismuth anode. All these products have been characterized by infrared spectral data, elemental analysis and various physical properties. Current efficiencies of all these systems are quite high.
Authors and Affiliations
Harpreet Kaur, Baljit Singh
Keywords
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- EP ID EP392555
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