Excess Thermodynamic Properties and Molecular Interaction in Ternary Systems of Aniline at 303.15K
Journal Title: International Journal for Research in Applied Science and Engineering Technology (IJRASET) - Year 2016, Vol 4, Issue 9
Abstract
Densities and viscosities of ternary liquid mixtures of Aniline with two polar solvents viz. Methyl ethyl ketone and N, N-Dimethylformamide and three non-polar solvents viz. benzene, toluene and carbon tetra chloride as well as their pure components have been determined at constant temperature 303.15 K. Excess thermodynamic properties viz. the excess viscosity (ηE), the excess molar volume (VE), the excess Gibbs free energy of activation of flow (ΔGE#) and an interaction parameter d by Grunberg and Nissan, have been calculated as a function of composition of ternary mixtures. Results have been revealed as evidence of the type and magnitude of molecular interactions existing among the components. The values of (ηE) and (VE) are negative for all six systems over the entire range of composition. The values of (ΔGE#) and d are negative for the systems with methyl ethyl ketone as a second component, while it is positive for the systems with N,N-Dimethylformamide as a second component except at lower concentration of second component where the value of (ΔGE#) is negative.
Authors and Affiliations
Gunjan Maheshwari
Keywords
Related Articles
- EP ID EP22660
- DOI -
- Views 273
- Downloads 5
Achieving Anonymity with Fully Anonymous Attribute-Based Encryption and Controlling Access Privilege in Cloud
Cloud computing could be a revolutionary computing paradigm, that allows versatile, on-demand, and inexpensive usage of computing resources, however the info is outsourced to some cloud servers, and varied privacy consi...
Simulation and Analysis of Microstrip Patch Antenna Using AN-SOF Professional
In this modern era, the development in wireless technology has caused a drastic change in size and weight of antenna used for communication. This paper shows the simulation of Microstrip patch antenna using AN-SOF PROF...
slugExperimental Investigation of Shell and Tube Heat Exchanger Using Bell Delaware Method
A heat exchanger is a device that is used to transfer thermal energy between two or more fluids, between a solid surface and a fluid, or between solid particulates and a fluid, at different temperatures and in thermal c...
Solution of Third Order Korteweg -De Vries Equation by Homotopy Perturbation Method Using Elzaki Transform
This Paper is discussing the theoretical approach of Elzaki transform [1] coupled with Homotopy Perturbation Method [3] that can be applied to higher order partial differential equations for finding exact as well as app...
Study of Oil Degrading Bacteria Isolated From Oil Contaminated Sites
Hydrocarbon degrading microorganisms were isolated from ten oil polluted areas in and around Navi Mumbai. Bushnell and Hass broth was used as selective enrichment medium with engine oil as a sole carbon and energy sourc...