GAS-PHASE SELECTIVE OXIDATION OF 2-CHLOROTOLUENE TO CHLORO-MALEIC ANHYDRIDE IN THE PRESENCE OF HETEROGENEOUS CATALYSTS
Journal Title: Azerbaijan Chemical Journal - Year 2016, Vol 0, Issue 1
Abstract
The activities of vanadium oxide catalysts with P, Mo, Sb additions drawn on SiO2 and Al2O3 in the reaction of oxidation of n-chlorotoluene has been iinvestigated. It is shown that the catalytiсal systems V–Mo–Sb–O/Al2O3 possess higher activities. Effect of the catalyst components activities on the reaction of oxidation mono-chlorotoluene has been determined. At ratio of the active components V:P=1:2–1:3 the catalytical system V–Mo–O/SiO2 display high activity at conversion of 2-chloro-toluenes equal to 85% , the yield of the basic product of oxidation MCMA makes up 24–28%
Authors and Affiliations
A. C. Efendi, E. M. Babayev, F. A. Yunisova, N. F. Aykan, B. A. İsmayilova
Keywords
Related Articles
- EP ID EP425959
- DOI -
- Views 132
- Downloads 0
PHASE EQUILIBRIUM IN QUASI-TERNARY SYSTEM InAs2SSe3–InAs2S3Se–In3As2S3Se3
Phase equilibrium in the systems InAs2S3Se–InAs2SSe3, InAs2SSe3–In3As2S3Se3, InAs2S3Se–In3As2S3Se3, InAs2S2Se2–In3As2S3Se3, (InAs2S3Sе)0.70(In3As2S3Se3)0.30 (е4)–(InAs2SSe3)0.60(In3As2S3Se3)0.40 (e3) were studied using...
SYNTHESIS OF NOVEL MANNICH BASES ON THE BASE OF 1-PHENOXY-3-PROPYLTHIOPROPANE-2-OL AND SECONDARY AMINES
The condensation of 1-phenoxy-3-propylthiopropan-2-ol with formaldehyde and secondary aliphatic, as well as heterocyclic amines, has led to the formation of new aminomethoxy derivatives of 1-phenoxy-3-propylthiopropane w...
SYNTHESIS OF 2-HYDROXYPROPYL-1,3-bis-ESTEROSULPHOIMIDES OF SACCHARIN-5- AND -6-CARBOXYLIC ACID
The interesterification reaction of the ethyl (I) and isopropyl (II) ethers of sulphoimides of saccharin-5- and -6-carboxylic acids with glycerine has been studied. The corresponding 2-hydroxypropyl-1,3-bis- esterosulpho...
SYNTHESIS OF NANOSTRUCTURES ON THE BASIS OF DIAZACROWN ETHER AND MAGNETITE NANOPARTICLES LOADED BY CEPHALOSPORIN ANTIBIOTICS
Synthesis of hydroxyl containing azacrown macrocycles (MC) that is able to mimic the properties of natural siderophores has been perfomed. On the basis of synthesized MC the supramolecular ensembles with magnetite nanopa...
SYNTHESIS AND PROPERTIES OF NEW SURFACTANTS BASED ON COTTON–SEED OIL TRIGLYCERIDES, ETHANOLAMINES AND ORTOPHOSPHORIC ACID
By interaction of cotton-seed oil triglycerides with monoethanolamine monoethylolamide of cotton-seed oil acid fraction is obtained which is further phosphated by orthophosphoric acid. The obtained phosphate-derivative i...