Green synthesis of nano polypyrrole using urea-hydrogen peroxide
Journal Title: Iranian Chemical Communication - Year 2015, Vol 3, Issue 3
Abstract
Polypyrrole is one of the most useful conductive polymers, but green synthesis of this polymer has been restricted until now. The objective of the present paper is green synthesis of nano polypyrrole (PPy) by oxidative polymerization using urea-hydrogen peroxide. It was found that conductivity and morphology of polypyrrole are highly dependent on the reaction conditions such as the molar ratio of oxidized to monomer, temperature, reaction time, kind of solvents, the presence of a catalyst such as p-toluene sulfonic acid, and specially concentration and addition time of hydrochloric acid. After understanding the relationship between these factors, we turned this enormous variability into improved polypyrrole properties.
Authors and Affiliations
Fariba Heidarizadeh, Saeed Asadipour Saeed Asadipour
Synthesis of HA nanoparticles in the presence of anionic and cationic polyelectrolyte
Nanosized hydroxyapatite (HA) powders have been synthesized by an inverse microemulsion system using cyclohexane, an anionic surfactant and aqueous solutions of calcium nitrate tetrahydrate and biammonium hydrogen phosph...
Synthesis and characterization of termini azobenzene dendrimer
Some organic molecules can be isomerized upon photoirradiation and when accompanied by a change in the visible absorption spectrum, it is called photochromism. Azobenzenes are important part of molecular machines and nan...
Synthesis and characterization of 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-one
New 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-one (2a) was synthesized in good yield by the Petrenko–Kritchenko reaction of 2, 2'-((3-hy...
Simultaneous determination of Tropaeolin O and brilliant blue in food samples after cloud point extraction
In this study, a simple and low-cost method was developed for extraction and pre-concentration of brilliant blue(BB) and Tropaeolin O(TO) in food samples using cloud point extraction (CPE) prior to spectrophotometric det...
ZnFe2O4 nanoparticle: Synthesis and photocatalytic activity under UV-vis and visible light
In the present work, the ZnFe2O4 nanoparticle has been successfully synthesized. The obtained sample was characterized by X-ray diffraction (XRD), emission scanning electron microscopy (FE-SEM) and its optical property w...