Heterobimetallic Aryloxides of Titanatranes with Aluminum Alkyls for Ring opening polymerization (ROP) of rac-Lactide
Journal Title: Archives of Organic and Inorganic Chemical Sciences - Year 2018, Vol 1, Issue 2
Abstract
Olefin polymerization catalysis [1a-1b] continues to be an area of considerable importance to both the academic and industrial communities, and a wide range of reports are appearing on the efficient catalyst designs and application in various catalytic systems. Recently, the work on bimetallic complexes and in particularly bimetallic oxides is gaining considerable attention due to the “cooperativity” or “communication” between neighboring repeating units [2a-2d]. Since heterometallic alkoxides are potential molecular precursors of multicomponent oxides, they are thus of interest for applications in catalysis as well as in material science. Heterometallic alkoxide derivatives have been postulated to act as catalysts in Ziegler-Natta polymerization [3a,3b] or olefin metathesis reactions, [3c] and exhibit high activity and produce polymers with different microstructure. These heterometallic complexes were also found active in nitrogen activation,” but detailed characterization is lacking [4].
Authors and Affiliations
Prabhuodeyara M Gurubasavaraj
Keywords
Related Articles
- EP ID EP576756
- DOI 10.32474/AOICS.2018.01.000110
- Views 88
- Downloads 0
Advanced Oxidation Processes (AOPs) by Bismuth Oxyhalides for Environmental Remediation Using Solar Energy: Enhancing Material Property through Synthesis
To combat air and water pollution with green chemistry is one of the major issues. Several research groups, worldwide, are today engaged in the design and development of new photocatalytic materials which can act to make...
The Functionalization of Trialkoxo Hexavanadates, the Treasure at the End of the Great Route
Polyoxometalates are well-known for the unique topological structures and functional activities of the pure inorganicor inorganic-organic clusters. As an important branch of polyoxometalates chemistry, polyoxovanadates (...
Two Step Conversion of Ferulic Acid to Vinyl Phenol
The cereal industries produce several million tons of cereal brans every year which are good source of ferulic acid. There was no such chemical route to convert ferulic to vinyl phenol directly. Therefore, an alternative...
Role of Combinatorial, Medicinal & Biological Chemistry in Drug Discovery Development: An Introduction
Combinatorial chemistry, a new approach for greatly reducing the time for the discovery of newer organic motifs, has been developed over the last few years. Combinatorial chemistry (Figure 1) is a technique...
Chloride-Induced Highly Active Catalyst for Methyl Esterification of Alcohols
In recent decades, Au catalysts have received growing attentions and been widely applied in many important research fields [1], since good performance of Au catalysts was discovered [2]. However, the controllable prepara...