Heterobimetallic Aryloxides of Titanatranes with Aluminum Alkyls for Ring opening polymerization (ROP) of rac-Lactide
Journal Title: Archives of Organic and Inorganic Chemical Sciences - Year 2018, Vol 1, Issue 2
Abstract
Olefin polymerization catalysis [1a-1b] continues to be an area of considerable importance to both the academic and industrial communities, and a wide range of reports are appearing on the efficient catalyst designs and application in various catalytic systems. Recently, the work on bimetallic complexes and in particularly bimetallic oxides is gaining considerable attention due to the “cooperativity” or “communication” between neighboring repeating units [2a-2d]. Since heterometallic alkoxides are potential molecular precursors of multicomponent oxides, they are thus of interest for applications in catalysis as well as in material science. Heterometallic alkoxide derivatives have been postulated to act as catalysts in Ziegler-Natta polymerization [3a,3b] or olefin metathesis reactions, [3c] and exhibit high activity and produce polymers with different microstructure. These heterometallic complexes were also found active in nitrogen activation,” but detailed characterization is lacking [4].
Authors and Affiliations
Prabhuodeyara M Gurubasavaraj
Keywords
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- EP ID EP576756
- DOI 10.32474/AOICS.2018.01.000110
- Views 63
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