Inhibition effect of polyvinyl butyral on crystallization of polypropylene

Journal Title: Polyolefins Journal - Year 2018, Vol 5, Issue 2

Abstract

In this work, a series of polypropylene/polyvinyl butyral (PP/PVB) blends were prepared by melt-blending process, at PVB loadings 3 wt%, 10 wt%, and 30 wt%. The effects of PVB on crystallization behavior of PP were investigated by differential scanning calorimetry (DSC), and polarized optical microscopy (POM). The isothermal crystallization kinetics were analyzed by Avrami equations. It was found that the addition of PVB strikingly reduced the overall crystallization rate of PP. The POM results further indicated that the crystallization rate of PP/ PVB was significantly reduced by reducing the nucleation density of PP with the addition of PVB. The fractured surface morphology of PP/PVB blends was characterized by scanning electron microscopy (SEM), and the results showed that the PVB was uniformly dispersed in the PP matrix as small spherical particles, with a good dispersion and dimensional stability.

Authors and Affiliations

Jun Huang, Guanghua Tian, Huayi Li, Lei Li, Qian Li, He Huang, Shuirong Zheng, Youliang Hu

Keywords

Related Articles

Influence of branching on the rheology and morphology of melt state long-chain branched polypropylene/polybuten-1 blends

In this study, the compatibility of polypropylene (PP)/polybutene-1 (PB-1) homopolymer blends before and after a long-chain branching process was studied. The blends were prepared and long-chain branched directly via a r...

Addition of a second alcohol in magnesium ethoxide synthesis as a way to vary the pore architecture of Ziegler-Natta catalysts

In Ziegler-Natta olefin polymerization, the pore architecture of catalysts plays a crucial role in catalytic performances and polymer properties. While the type of preparation routes (such as chemical reaction and soluti...

Mathematical modeling the effect of catalyst initial shape and the crack pattern in olefin copolymerization

A two-dimensional (2D) single particle model for the copolymerization of propylene-ethylene with heterogeneous Ziegler-Natta catalyst is developed. The model accounts for the effects of the initial shape of the catalyst...

High porosity polyethylene aerogels

Monolithic aerogels of high molecular weight polyethylene (Mw= 3x106- 6x106 g/mol) have been prepared by solvent extraction with supercritical carbon dioxide from thermoreversible gels prepared in decalin. These low dens...

The effect of high-energy electron beam on drawn and undrawn high density polyethylene fibers

HDPE monofilaments were obtained using different extruders and drawn by post-extruder equipments. After solidification, drawn and undrawn monofilaments (draw ratio 7:1) were irradiated with 10 MeV electron beams in air a...

Download PDF file
  • EP ID EP312079
  • DOI 10.22063/poj.2018.1979.1106 INTRODUCTION
  • Views 114
  • Downloads 0

How To Cite

Jun Huang, Guanghua Tian, Huayi Li, Lei Li, Qian Li, He Huang, Shuirong Zheng, Youliang Hu (2018). Inhibition effect of polyvinyl butyral on crystallization of polypropylene. Polyolefins Journal, 5(2), 141-151. https://europub.co.uk/articles/-A-312079