Interaction of the components in the Gd-Mn-Sn ternary system at 873 and 673 K
Journal Title: Фізика і хімія твердого тіла - Year 2018, Vol 19, Issue 1
Abstract
The interaction of the components in the Gd-Mn-Sn ternary system was studied using the methods of X-ray and microstructure analyses, in the whole concentration range. The isothermal sections of the phase diagrams of the Gd-Mn-Sn system were constructed at 873 and 673 K. At both temperatures of investigation the Gd-Mn-Sn system is characterized by formation of two ternary compounds: GdMn6Sn6 (MgFe6Ge6 structure type, space group P6/mmm) and Gd4Mn4Sn7 (Zr4Co4Ge7 structure type, space group I4/mmm). The formation of the interstitial solid solution GdMnхSn2 based on GdSn2 (ZrSi2-type) binary compound was observed up to 10 at. % Mn at 873 K and 673 K. The existence of the substitutional solid solution based on GdMn2 (MgCu2-type) was observed up to 5 at.% Sn and 3 at. % Sn at 873 K and 673 K, respectively.
Authors and Affiliations
L. P. Romaka, Yu. V. Stadnyk, V. V. Romaka, M. Konyk, R. Serkiz
Keywords
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- EP ID EP328218
- DOI 10.15330/pcss.19.1.60-65
- Views 47
- Downloads 0
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