MOLECULAR ABSORPTION SPECTROSCOPY IN THE UV-VIS REGION FOR THE QUINOLINE-N-OXIDE, NICOTINAMIDE-N-OXIDE AND 2,2-DITHIOBISPYRIDINE-N-OXIDE LIGANDS
Journal Title: Periódico Tchê Química - Year 2017, Vol 14, Issue 27
Abstract
Required The purpose of this study was to analyze and quantify spectral parameters, the absorption bands, specifically in the uv-visible region of some N-oxide ligands. From the spectra, the area under the absorption band, the molar absorptivity, the integrated absorption coefficient and the oscillator strength by the Gaussian approximation method were calculated for each of them, using the proposed evaluation by Drago and Figgs. According to the obtained results, it can be concluded that the heterocyclic compounds studied absorb very well electromagnetic radiation in the ultraviolet region. For the ligands QUI-NO and NIC-NO it was observed that there are two types of bands, primary and secondary, being transitions of type p ® p * and n ® p*, respectively. For DITBIS-NO, there was only one primary band (transition 1) and two additional shoulders, which had the highest observed absorbance coefficient. These ligands are expected as potential electron donors in complex systems whose purpose is to change the energy levels of the electronic system in order to promote a better utilization of the absorbed energy and therefore a better efficiency.
Authors and Affiliations
Francisco Jose Santos LIMA
Keywords
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