Molecular Association of 2, 3-Dichloroaniline and 2-Ethoxyethanol Using Microwave Frequency in GHZ
Journal Title: International Journal of engineering Research and Applications - Year 2018, Vol 8, Issue 12
Abstract
Densities, viscosities, refractive index, dielectric constant (ε') and dielectric loss (ε") of 2,3-dichloroaniline (2,3- DCA)+2-ethoxyethanol (2-EE) for different mole fractions of 2,3-dichloroaniline in binary mixture have been measured at single microwave frequency 10.985 GHz by Surbers technique at microwave X-band. The values of dielectric parameters (ε') have been used to evaluate the molar polarization (P12), loss tangent (tan δ) explain the formation of complexes in the system. It is found that dielectric constant (ε'), dielectric loss (ε"), loss tangent (tan δ), molar polarization (P12) varies non-linearly but activation energy (Ea),viscosity (η), density (ρ) and refractive index (n) varies linearly with increasing mole fraction in binary mixture of 2,3-dichloroaniline+2- ethoxyethanol. Hence, solute-solvent molecular associations have been reported.
Authors and Affiliations
B. G. Nemmaniwar
Keywords
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