OXIDATIVE DEHYDROGENATION OF CYCLOHEXANE OVER MODIFIED ZEOLITE CATALYST
Journal Title: Azerbaijan Chemical Journal - Year 2016, Vol 0, Issue 4
Abstract
It has been investigated the catalytic activities of modified zeolites in the reaction of oxidative dehydrogenation of cyclohexane. It has been determined that the CuZnCoCr-clinoptilolite (Cu2+-0.5%; Zn2+-0.2%; Co2+--0.1%; Cr3+-0.1%) polimetale zeolite catalyst shows higest activity in this reaction. The kinetic scheme of mehanism of reaction has been suggested and kinetic model of this process has been developed. It has been calculated the kinetic parametres of kinetic model
Authors and Affiliations
A. M. Aliyev, Z. A. Shabanova, U. M. Najaf-Quliyev, A. I. Karimov
THE ROLE OF STRUCTURANTS IN THE PROCESS OF FORMATION OF STRUCTURE AND PROPERTIES OF POLYMER COMPOSITES BASED ON RANDOM POLYPROPYLENE AND MINERAL FILLERS
The influence of the multifunctional organic structure forming and mineral fillers on the structural features and physico-mechanical properties of polymer composites based on statistical copolymer of ethylene with p...
CONTROL OF THE PROCESS OF STYRENE POLYMERIZATION IN NONSTATIONARY CONDITIONS
The mathematical model of the process of suspension polymerization of styrene has been developed under nonstationary conditions caused by a poisoning effect on the initiator of phenylacetylene entering to polymerization...
COLLOIDAL CHARACTERIZATION AND SORPTION OF COBALT(II) AND CADMIUM IONS FROM MODEL SOLUTIONS ON MODIFIED BENTONITE
We studied sorption of cadmium and cobalt(II) ions from model solutions on natural and thermally processed Na-bentonite at the range 20–650C. In different temperatures on both natural and Na-bentonites equilibrium consta...
CURRENT STATE OF CATALYTIC OXIDATION OF ALKYLAROMATIC CHLOROHYDROCARBONS AND ITS DEVELOPMENT PROSPECTS
The study of synthesizing alkylaromatic chlorohydrocarbons, as well as current state of their catalytic oxidation is considered. The posibility of catalytic oxidation of chlorotoluenes in the presence of varie-tyheterog...
A STUDY OF THE KINETICS AND MECHANISM OF THE SELECTIVE OXIDATIVE DEHYDROGENATION REACTİON OF CYCLOPENTANE TO CYCLOPENTADIENE-1,3 OVER MODIFIED ZEOLITE CATALYSTS
The reaction of cyclopentane has been studied on HY zeolite at 3800C. Cyclopentene and cyclopentadiene formed a stable initial product by the dehydrogenation of the raw material, although molecular hydrogen was not found...