Preparation and characterization of polyethylene/ glass fiber composite membrane prepared via thermally induced phase separation method
Journal Title: Polyolefins Journal - Year 2017, Vol 4, Issue 2
Abstract
Grinded glass fiber (GGF) embedded high density polyethylene (HDPE) membranes were prepared via thermally induced phase separation method. FESEM images showed that all the membranes had leafy structure, indicating a solid-liquid mechanism during phase separation. The results of EDX and TGA analyses confirmed that the fibers were dispersed in the HDPE matrix uniformly. Normalized water flux of the membranes increased from 1 for the neat HDPE membrane to more than 4 for 10 wt% GGF/HDPE membrane. Moreover, the contact angle decreased from 129° to 94° as the GGF content increased in the membranes, showing an improvement in the surface hydrophilicity of the membranes. The AFM results revealed that the surface roughness of the membranes was increased with increasing the GGF content. The results of abrasion test revealed that the GGF/HDPE membranes had a more abrasion resistance than the neat HDPE membrane. Finally, the fouling behavior of the membranes was investigated by the filtration of BSA protein solution and the results showed that with increasing the glass fiber content, total fouling ratio decreased from 90% for the neat HDPE membrane to 62% for 10 wt% GGF/HDPE membrane, indicating that the antifouling properties of the membranes were improved due to the presence of glass fiber.
Authors and Affiliations
Ali Behboudi, Yoones Jafarzadeh, Reza Yegani
The relationship among changes in microstructure, active sites behavior and properties in the propylene polymerization with a 4th generation Ziegler-Natta catalyst
Three polypropylene samples (1-3) were synthesized with a 4th generation Ziegler-Natta catalyst in the presence of cyclohexyldimethoxymethylsilane (donor c), dicyclopenthyldimethoxysilane (donor d) and diisopropyldimetho...
Thermal-insulation performance of low density polyethylene (LDPE) foams: Comparison between two radiation thermal conductivity models
The loss of energy, especially in industrial and residential buildings is one of the main reasons of increased energy consumption. Improving the thermal insulation properties of materials is a fundamental method for redu...
Compression, supramolecular organization and free radical polymerization of ethylene gas
At low pressure, ethylene gas consists of single translating and rotating molecules and behaves as an ideal gas. With decrease of free volume by compression, various rotating supramolecular particles are formed, which re...
Effect of NH3/methylaluminoxane/dodecylamine modifiednanoclay on morphology and properties of polyethylene/ clay nanocomposites prepared by in-situ polymerization
This study presents methods for treating a kind of nanoclay and investigates the effects of methylaluminoxane (MAO) exposure time and or dodecylamine (DDA) reflux time on in-situ polymerization of ethylene in the presenc...
Influence of diethyl zinc on ethylene-norbornene copolymerization
Ethylene-norbornene copolymers were synthesized with a homogeneous catalyst system based on bis(imino) pyridine iron with the addition of diethyl zinc (DEZ) as alkyd transfer agent to promote immortal copolymerization. T...