Preparation and Crystal Structure Determination of Zinc(II)bromide Complexes at the Presence of Various Ligands
Journal Title: Chemical Methodologies - Year 2019, Vol 3, Issue 0
Abstract
In this paper, we report the syntheses and crystal structure determination of three mononuclear and four-coordinated zinc (II) bromide complexes with chemical formula of [Zn(tsc)2]Br2 (1), Zn(PPh3)2Br2 (2) and Zn(Brcatsc)Br2 (3). The synthesized complexes are characterized by elemental analysis (CHN) and their crystal structures are investigated by single crystal X-ray diffraction. In complex 1, the TSC coordinates to the zinc (II) ion as a bidentate ligand via N and S atoms. In complex 3, the thiosemicarbazone ligand Brcatsc coordinates to zinc (II) ion as a monodentate ligand via S atom. In these complexes, the zinc (II) ion coordinated in a distorted tetrahedral coordination geometry.
Authors and Affiliations
Ali Akbar Dehno Khalaji, Ensieh Shahsavani, Michal Dusek, Monika Kucerakova, Wolfgang Hornfeck
Keywords
Related Articles
- EP ID EP577269
- DOI 10.33945/SAMI/CHEMM.2019.5.2
- Views 96
- Downloads 0
Investigation of NMR Parameters of para-Sulfonato-calix[4]arene by HF Calculation
Conformationally-rigid para-sulfonato-calix[4]arene (C28H24O16S4) was isolated. The NMR parameters of the structure of calix[4]arenes have been compared. The study of organic structures to form nanoporous materials is a...
Development and Validation of a Stability Indicating HPLC Assay Method for Determination of Warfarin Sodium in Tablet Formulation
The objective of the current study was to developed simple, precise and accurate isocratic reversed-phase stability indicating high performance liquid chromatography [HPLC] assay method validated the for determination of...
In Silico Study of Metoclopramide as A Small Molecule of Dopamine D2 Receptor: a Quantum-Mechanical (QM) Based Molecular Docking Treatment
The present research exploration will contain studying the molecular structure, bonds nature, stability, reactivity and electronic properties of the title molecule.The molecular optimization and all theoretical computati...
10.22034/CHEMM.2018.66185
A new LC-MS based method was developed to detect three potential genotoxic impurities namely, N',N'''-(4,6-dichloropyrimidine-2,5-diyl)bis[N,N-dimethyl(imidoformamide)]} (Impurity-I), {N-(2-amino-4-chloro-6-{[(1S,2R)-2-(...
Lithium–functionalization of Pyrrole–n–carboxylic Acids (n=1, 2, 3)
Functionalization processes of neutral and ionic forms of the singular lithium element (Li/Li+) by the pyrrole–n–carboxylic acid (PnCA; n=1, 2, 3) have been investigated based on the quantum chemical density functional t...