Preparation , Characterization, and Theoretical Treatment Complexes Of Some Transition Metals with N5 Acyclic Derived From 2,6-diacetyl pyridine
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2013, Vol 2, Issue 2
Abstract
  A series of transition metal complexes with [2,6-diacetimino-pheylenediamine –[2,2,diyl] pyridine ]of the general formula [MLCl]Cl , M= Co(II), Ni(II) and Cu(II) , respectively have been synthesized and fully characterized on the bases of C.H.N.M elemental analysis, 1HNMR , UV- Visible and FTIR spectra , in addition the structure of complexes was characterized by magnetic moments and molar conductance in DMSO solution ,and molar ratio of metal were also determined. From the above of these studies and measurements suggest an octahedral geometry around Co(II) , Ni(II) and Cu(II) .A theoretical treatment of the formation of complexes in the gas phase was studied, this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semi-empirical calculations.Â
Authors and Affiliations
Omar Al-Obaidi
Keywords
Related Articles
- EP ID EP652520
- DOI 10.24297/jac.v2i2.899
- Views 152
- Downloads 0
Activity and stability of immobilized Candida rugosa lipase on chitosan coated Fe3O4 nanoparticles in aqueous and organic media
Fe3O4 (magnetite) nanoparticles were prepared by coprecipitation method, coated by chitosan and functionalized by glutaraldehyde. Lipase enzyme from Candida rugosa was immobilized on the prepared particles via cross link...
INHIBITIVE BEHAVIOUR OF GREEN INHIBITOR IN POTABLE WATER DISTRIBUTION SYSTEM
The inhibition effect of amino trimethylene phosphonic acid (ATMP) and zinc ions on the corrosion of carbon steel in potable water distribution system was investigated. The corrosion inhibiting action was studied through...
Toxicological Impacts of Gas flaring and Other Petroleum Production Activities in Niger-Delta Environment
In this study, the concentrations of inducers of environmental toxicity such as heavy metals and polycyclic aromatic hydrocarbon and biomarkers of environmental toxicants such as oxidative stress enzymes/compounds and li...
Mechanical Properties of Randomly Oriented Calotropis Gigantea Fiber-Reinforced Phenol Formaldehyde Biocomposites
Mechanical properties such as tensile, flexural and impact, of randomly oriented Calotropis Gigantea Fiber (CGF) -reinforced Phenol Formaldehyde (PF) biocomposites were studied based on the five different fiber loadings...
The Influence of Excipients on the Physicochemical and Biological Properties of a Bactericidal, Labile Ester Prodrug in a Salt Form – A Case Study of Cefetamet Pivoxil Hydrochloride
The article presents an innovative approach to a bactericidal drug design based on a cephem prodrug analogue – cefetamet pivoxil hydrochloride. The emergence of cefetamet pivoxil hydrochloride excipient systems (mannitol...