Study of the Influence of Alkyl Chain Cation Solvent Interactions on the Slope of ϕv v/s √C Curves in 1, 3-Butanediol-DMF Solvent Mixtures by Apparent Molar Volume Measurements

Journal Title: Chemical Science International Journal - Year 2017, Vol 19, Issue 3

Abstract

The concept of Frank’s hypothesis (that is the effect of large tetra alkyl ammonium iodides on the solvent structure, especially in the ion – ion and ion – solvent interactions) was found to be not applicable when water was replaced by one of organic solvent. That is, if study involves ion- ion and ion – solvent interactions in 1, 3 – Butane diol – DMF solvent mixture. The densities of these mixture and some adding tetra alkyl ammonium iodide salts solutions at different concentrations (0.02 – 0.14 M) have been determined at 298.15 K using Magnetic Float Densitometer technique. The apparent molar volume (ϕv) and apparent molar volumes of transfer ∆ϕv0 (tr) of the electrolytes in above solvent mixtures were calculated. ϕv vs √C curves are plotted and explained the nature of molecular interactions by using slope (Sv) values. Also, the significant role of varying dielectric constants (ϵ) of the selected solvent mixtures in the ionic interaction is discussed.

Authors and Affiliations

Indu Saxena, Archna . , Rikkam Devi, Vijay Kumar, Sadhana Gautam, Jaya Tripathi

Keywords

Related Articles

Prediction of Generalised and Localised Carbon Steel Corrosion Using Improved Norsok and Papavinasam Models

In this study, Norsok and Papavinasam models have been improved so as to reduce the model limitations. The Norsok model was improved by accounting for 3 phase flow in calculating the wall shear stress and correcting for...

Evaluation of Elemental Pollution in Roadside Dust Northeast of Nairobi Major Highway and at Thika Town, Kenya

Aims: To evaluate the level of elemental pollution in roadside dust. Study Design: Dust samples were collected along Thika highway at Roysambu and at Thika town. Place and Duration of Study: Department of chemistry, gov...

Mathematical Modelling, Energy and Exergy Analysis of Tomato Slices in a Mixed Mode Natural Convection Solar Dryer

This paper reports the drying kinetics of tomato (Lycopersicon esculentum) with different drying loads in a fabricated mixed mode natural convection solar dryer. The energy utilization ratio (EUR) and exergetic efficienc...

Phenolic Foam Reinforced by Cedar’s Resin

Recently phenolic foams have been received much attention because of their excellent properties including flame resistance, low density, high thermal stability over a broad temperature range and low generation of toxic g...

Assessment of Some Physicochemical, Bacteriological and Heavy Metals Properties of Effluent from a Chemical Industry in Niger Delta, Nigeria

Some physicochemical, heavy metals and bacteriological parameters of effluent samples from a chemical industry in Niger Delta, Nigeria, in two sampling seasons (Wet and Dry seasons) were assessed in this work using stand...

Download PDF file
  • EP ID EP319712
  • DOI 10.9734/CSIJ/2017/33860
  • Views 74
  • Downloads 0

How To Cite

Indu Saxena, Archna . , Rikkam Devi, Vijay Kumar, Sadhana Gautam, Jaya Tripathi (2017). Study of the Influence of Alkyl Chain Cation Solvent Interactions on the Slope of ϕv v/s √C Curves in 1, 3-Butanediol-DMF Solvent Mixtures by Apparent Molar Volume Measurements. Chemical Science International Journal, 19(3), 1-10. https://europub.co.uk/articles/-A-319712