Supramolecular Solvent-Based Microextraction of Propachlor and Prometryn Herbicides in Soil Samples Prior to Liquid Chromatographic Analysis
Journal Title: Cumhuriyet Science journal - Year 2018, Vol 39, Issue 4
Abstract
Supramolecular solvents (SUPRASs) are the nano-structured liquids generated from amphiphiles through a self-assembly process, and constitute an alternative to molecular organic solvents with becoming more environmentally friendly in sample preparation step. In this study, a SUPRAS-based analytical method has been proposed for the microextraction of propachlor and prometryn herbicides in soil samples. The method involved the vortex mixing of the 300 mg of soil sample with 300 µL of SUPRAS for 8 min, subsequent centrifugation for the phase separation, and direct analysis of the SUPRAS phase by liquid chromatography with ultraviolet detection. Under optimal extraction conditions, the extraction recoveries for the herbicides ranged from 81 to 87 %. The method detection limits for propachlor and prometryn were 0.07 and 0.01 μg/g, respectively. Relative standard deviations obtained for the herbicides were less than 8.8 % and 12.1 % for intra-day and inter-day precisions, respectively. The microextraction of related herbicides from soil samples collected from the Zonguldak region was carried out efficiently. The recoveries obtained from spiked soil samples ranged from 80 to 108 %.
Authors and Affiliations
Gözde DURSUN, Elif YILDIZ, Hasan ÇABUK
Keywords
Related Articles
- EP ID EP488416
- DOI 10.17776/csj.452956
- Views 71
- Downloads 0
Linear And Nonlinear Intersubband Optical Absorptions In Multiple Quantum Wells Under The External Fields
In this study, the effects of the external fields (electric and tilted magnetic fields) and well parameters on the optical absorption coefficients in GaAs/GaAlAs multiple (five) quantum wells under the applied electric a...
On Razzaboni Transformation of Surfaces in Minkowski 3-Space
In this paper, we investigate the surfaces generated by binormal motion of Bertrand curves, which is called Razzaboni surface, in Minkowski 3-space. We discussed the geometric properties of these surfaces in with respec...
The Oxidation of 4-(4-Formylphenoxy) Phthalonitrile to 4-(4-Carboxylphenoxy) Phthalonitrile at Ambient Conditions
The substituted phthalonitriles have been used to prepare soluble phthalocyanine species in recent years. One of the most used phthalonitrile derivatives for the target product is 4-nitrophthalonitrile. In this study 4-(...
Immobilized Nanoparticles on Polymeric Carriers for Removal of Reactive Textile Dyes in Aqueous Media
In the waste water treatment, especially in the removal of textile dyes from aqueous media, it is known that photocatalytic oxidation technique has tremendous advantages compared to conventional techniques, such as quick...
Streamline Topology of Axisymmetric Flow Near Non-Simple Singular Point
The aim of this paper is to obtain streamline patterns of axisymmetric flow and their bifurcations for 2-D incompressible flows close to non-simple singular point. The streamlines of a Hamiltonian vector field system are...