Synthesis and characterization of a new 3D supramolecular structure constructed by Waugh-type polyoxoanion and lanthanide ions

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Synthesis and characterization of a new 3D supramolecular structure constructed by Waugh-type polyoxoanion and lanthanide ions

Journal Title: Science Paper Online - Year 2010, Vol 5, Issue 3

Abstract

A new 3D supramolecular structure [(CH3)4N]2Nd[HMnMo9O32]•6H2O (1) has been obtained in aqueous solution by reaction of the Waugh-type polyoxoanion [MnMo9O32]6- with Nd3+ ions, and characterized by IR, UV, element analysis, TG and single-crystal X-ray analysis. The crystal data for compound 1: Cubic, space group Fm-3m, a = b = c = 1.65891(1) nm, α = β = γ = 90.00(0)°，V = 4.5653(9) nm3，Z = 4.

Authors and Affiliations

Huaqiao Tan, Enbo Wang

Keywords

Waugh-type polyoxoanion lanthanide single-crystal structure

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EP ID EP149958
DOI -
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