Synthesis and physico-chemical studies of a novel noncentrosymmetric heptacoordinated cadmium(II) compound containing a tripodal amine, CdCl2[N(C2H6N)3]2
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 10, Issue 10
Abstract
A new noncentrosymmetric Cd(II) complex with thetripodal amine tris(2-aminoethyl)amine, CdCl2[N(C2H6N)3]2, has been prepared and characterized by single crystal X-ray diffraction, solid state NMR and IR spectroscopies. In the complex, the Cd(II) ion is surrounded by sevennitrogen atoms. The organic molecule acts as both a tri-and a tetradentate ligand. The cationic complexes are linked to each other forming layers parallel to the (a, b)plan. The Cl- counter ions occupy the cavities created inside these layers. The 13C CP-MAS NMR spectra are in agreement with the X-ray structure. DFT calculations allow the attribution of the carbon peaks to the differentatoms.The vibrational absorption bands were identified by infrared spectroscopy and DFT calculations allowed their attributions.
Authors and Affiliations
M. Ben Nasr, K. Kaabi, P. S. Pereira Silva, F. Lefebvre, C. Ben Nasr
Keywords
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- EP ID EP652814
- DOI 10.24297/jac.v10i10.873
- Views 121
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