SYNTHESIS AND PROPERTIES OF 2-SUBSTITUTED 1,4-ENYNE CHLOROHYDRINS

Journal Title: Azerbaijan Chemical Journal - Year 2017, Vol 0, Issue 3

Abstract

By interaction of 2-substituted 1,4-enyne alcohols with 1-chloro-2,3-epoxy propane in the presence of boron trifluoride etherate there have been synthesized 2-substituted 1,4-enyne chlorohydrin by dehydrochlorination of which epoxy-1,4-enynes and epoxy-1,3,4-triens have been prepared. The addition reaction of the methyl diethyl silane to epoxy-1,4-enynes leads to the formation of mixture of silicoorganic epoxy-1,4-dienes

Authors and Affiliations

A. M. Garamanov, M. Sh. Gurbanov, A. F. Guliyeva, S. N. Allakhverdiyeva

Keywords

Related Articles

NITROGEN FIXATION AT CONJUGATED OXIDATION

Using the new principle of nitrogen oxidation by hydroperox¬ide has helped in discovering a new method of nitrogen fixation, mainly shaped as N2O, other oxides with low admixtures or nitrogen-containing acids under condi...

CONTROL OF THE PROCESS OF THE DEHYDROGENATION OF ETHYLBENZENE IN STYRENE, FLOWING UNDER NONSTATIONARY CONDITIONS

A new method, different from the industrial one is suggested, for carrying out the process of dehydrogenation of ethylbenzene in styrene, consisting in gradual lowering of the temperature of the raw material at the inlet...

USE OF METAL-ZEOLITES AS A CATALYST IN REACTION OF OXIDATIVE DEHYDROGENATION OF NAPHTHENES

Oxidative dehydrogenation of cyclohexane into 1,3-cyclohexadiene and methylcyclohexane into 1-methyl-1,3-cyclohexadiene has been found possible by use of clinoptilolite (CL) {Cu2+ (0.5 mas. %), Zn2+ (0.2 mas. %), Co2+...

OXIDATIVE CONVERSION OF PROPYLENE TO ACROLEIN ON METAL ZEOLITE CATALYSTS

Catalytic activity of modified zeolites in the reactions of oxidative conversion of propylene to acrolein was studied. It was established that Ni-clinoptilolite (1% Ni2+) exhibits high activity in the studied reaction....

SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM(V) IN THE CLAY SAMPLES

Complexation of vanadium(V) with a reagent synthesized based on pyrogallol – 2,3,4-trihydroxy-5-sulphoazonaphtalin has been studied by spectrophotometric method. It was found that at pH=5, λmax = 437 nm intensively colo...

Download PDF file
  • EP ID EP418623
  • DOI -
  • Views 98
  • Downloads 0

How To Cite

A. M. Garamanov, M. Sh. Gurbanov, A. F. Guliyeva, S. N. Allakhverdiyeva (2017). SYNTHESIS AND PROPERTIES OF 2-SUBSTITUTED 1,4-ENYNE CHLOROHYDRINS. Azerbaijan Chemical Journal, 0(3), 43-47. https://europub.co.uk/articles/-A-418623