Synthesis, characterization and antibacterial activity of ethylene di-amine and 2-hydroxybenzadehyde Schiff base and its metal complexes

Journal Title: Journal of Chemistry and Environment - Year 2022, Vol 1, Issue 1

Abstract

A number of modern techniques have been developed for the synthesis of Schiff bases. We reported the synthesis of ethylene di-amine and 2-hydroxybenzadehyde Schiff base (SB) via the condensation method. To remove phenolic hydrogen to form Schiff base it was reacted with sodium hydroxide and then treated with M(II) chloride (M=Fe, Cu, Zn, Ni and Sn) to fabricate their respective metal complexes. The synthesis of SB metal complexes and detailed functional group characterization were validated via Fourier transform infrared (FT-IR) spectroscopy. In the final SB, FT-IR results revealed a vibrational peak at 1614 cm-1, which was credited to the –C=N part. The absence of a vibration band for –OH vibration on 1613 cm-1 and the presence of a novel band in the 659 to 586 cm-1 range were due to the metal-oxygen bond, confirming the synthesis of metal complexes. The Schiff base showed high antibacterial activity against E. coli, Pseudomonas aeruginosa, Salmonella typhi, S.aureus and Bacillus whereas Streptococcus was found resistant. Cu, Fe and Sn coordination improved Schiff base activity while Ni coordination did not affect the activity. Similarly, Fe and Sn complex had no effect on E. coli. In comparison with standard Ciprofloxacin, the activities of respective metal complexes were low.

Authors and Affiliations

Muhammad Junaid, Jianhua Yan, Zhongquan Qi, Muhammad Haroon

Keywords

Related Articles

Simulation for migration and treatment of groundwater contamination in coal mining subsidence area: A case study of Datong dump, Huainan, China

The liquid that seeps into the earth from landfills and removes garbage is called landfill leachate. Pollutants like organic and inorganic chemicals, xenobiotic substances, etc. are found in landfill leachate which conta...

Physio-chemical and Thermal Characterization of Demineralized Poultry Litter using Mechanical Sizing Fractioning, Acid Solvents, and Deionized Water

Poultry litter is an organic waste composed of manure, feathers, and bedding, containing both organic and inorganic elements. Inorganic elements corrode and agglomerate the reactors when poultry litter is thermally conve...

Sustainable Catalysis: Navigating Challenges and Embracing Opportunities for a Greener Future

Catalysis plays a crucial role in sustainable chemistry, as demonstrated in this review article. The introduction highlights the importance of catalysis in sustainability and summarizes catalysis research. In this review...

Synthesis of bimetallic iron ferrite and its applications in alcohol fuel cell

Fuel cell is a clean, safe, eco-friendly source of energy as an alternative to already existing energy resources like incineration of fossil fuel. Efficiency of fuel cell is high when platinum is used as an electrode mat...

Recovery Optimization of Plant Derived Antioxidants And Their Incorporation in Cosmetic Creams to Enhance Antioxidant Potential

Plants waste is enriched with valuable antioxidants. Extraction optimization, quantification of Total phenolic content (TPC) and evaluation of their anti-aging potential was the prime goal of this research study. Lime, N...

Download PDF file
  • EP ID EP713428
  • DOI https://doi.org/10.56946/jce.v1i01.34
  • Views 88
  • Downloads 0

How To Cite

Muhammad Junaid, Jianhua Yan, Zhongquan Qi, Muhammad Haroon (2022). Synthesis, characterization and antibacterial activity of ethylene di-amine and 2-hydroxybenzadehyde Schiff base and its metal complexes. Journal of Chemistry and Environment, 1(1), -. https://europub.co.uk/articles/-A-713428