Synthesis, Growth and characterization of Bis - glycine cobalt chloride dihydrate single crystal: A new semiorganic nonlinear optical material
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2016, Vol 12, Issue 22
Abstract
Single crystals of potential semiorganic nonlinear optical material of bis - glycine cobalt chloride dihydrate (BGCC) were grown by slow evaporation technique at room temperature. The structure of BGCC crystal was examined by single crystal X – ray diffraction analysis. The single crystal X – ray diffraction of BGCC reveals that the crystal belongs to monoclinic system with centrosymmetric space group. The powder X – ray diffraction analysis was carried out the reflection planes of the sample was confirmed and the peaks were indexed. Fourier transform infrared (FT – IR) spectroscopic analysis was used to confirm the presence of various functional groups in the grown crystal. UV – Vis – NIR spectral analysis of BGCC crystal shows that the crystal is transparent between the wavelengths 265 nm to 1100 nm. Vickers microhardness study revealed that the grown crystal belongs to soft material category. Dielectric constant and dielectric loss of BGCC crystal were measured in the frequency range of 100 Hz to 3 MHz. Thermal stability of the BGCC crystal was studied by thermogravimetric, differential thermal analysis and differential scanning calorimetric studies and found that the grown crystal is stable up to 220 °C.
Authors and Affiliations
L. Gobinathana, K. b Boopathy
Keywords
Related Articles
- EP ID EP653032
- DOI 10.24297/jac.v12i22.4721
- Views 134
- Downloads 0
Acid Attack On Hybrid Fiber Reinforced High Strength Concrete With Manufactured Sand and Coconut Shell
In this study, the acid attack test is performed on the fiber reinforced concrete incorporating with manufactured sand silica fume and coconut shell. The grade of concrete is M50. Silica fume is partially replaced with 1...
Highly selective potentiometric determination of Fe(III) ions using Tris-(1,2-diiminocyclohexylmethyl-5-Cl-2-hydroxyl benzaldehyde) based membrane electrode
A novel ion-selective poly(vinyl chloride) membrane sensor for Fe(III) ions based on Tris-(1,2-diiminocyclohexylmethyl-5-Cl-2-hydroxyl benzaldehyde) are reported in this paper. The electrode exhibits a good potentiometri...
IMPACT OF AGGRESSIVE CHEMICAL ENVIRONMENT AND CORROSION ON DURABILITY CHARACTERISTICS OF FIBRE REINFORCED CONCRETE
           Durability characteristics of concrete play an imperative role in the performance of the buildings. Concrete despite its versatility is known to have several limitations. It is weak in te...
Green synthesis of Novel Schiff bases derived from 2, 6 diamino pyridine – Characterization and Biological activity
Present work produces an excellent green route for the synthesis of Schiff bases derived from 2, 6 diamino pyridine, by using lemon juice as the catalyst. This method is experimentally simple, quick, clean and high yield...
Synthesis of Furopyrimidine Derivatives
Furopyrimidines have been known for many years and have been thoroughly examined in the recent years. The present review deals with description of the various synthetic routes for  furopyrimidine derivatives.