SYNTHESIS OF HALOGEN DERIVATIVES OF N-ARYLAMINOCARBONYL-1,4-BENZOQUINONE MONOIMINES
Journal Title: Вісник Одеського національного університету. Хімія - Year 2017, Vol 22, Issue 1
Abstract
The hydrohalogenation of N-arylaminocarbonyl-1,4-benzoquinone monoimines is optimal method to obtain the halogenated derivatives. This method allows obtaining the pure products in high yield with a halogen atom in the aminophenol ring. The bromination of N-arylaminocarbonyl-1,4-benzoquinone monoimines and their reduced forms allows obtaining of individual products only in several cases. The bromination allows synthesizing of products with a halogen atom not only in the aminophenol ring, but in the aryl moiety too. As a result of the experiment we have found the optimal conditions to synthesis the N-arylaminocarbonyl-1,4-benzoquinone monoimine derivatives containing halogen atom. The bromination and hydrohalogenation products with one free ortho-position toward to the imine carbon atom of the quinoid ring can be used as synthons in the synthesis of heterocyclic compounds – 1,3-benzoxazole derivatives.
Authors and Affiliations
S. A. Konovalova, A. P. Avdeenko, E. N. Lysenko
Keywords
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- EP ID EP334553
- DOI 10.18524/2304-0947.2017.1(61).94716
- Views 78
- Downloads 0
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