SYNTHESIS OF heme-DICHLOROSUBSTITUTED CYCLOPROPANES BY DICHLOROCYCLOPROPANATION OF LIQUID PYROLYSIS PRODUCTS OF THE OIL HYDROCARBONS
Journal Title: Azerbaijan Chemical Journal - Year 2016, Vol 0, Issue 2
Abstract
Under the conditions of interphase catalysis the dihlorcyclopropanation of fraction C5 of liquid pyrolysis products of the oil hydrocarbons was carried out and heme-dichlorosubstituted vinyl cyclopropanes and tetrachlorobicyclopropyls have been synthesized. The optimal conditions of preparation of these compounds have been found. The possibility of carrying out the dichlorocyclopropanation reaction of non-fractionated liquid pyrolysis products has been revealed and it has been shown that in this case, along with mono- and bis-adducts, the addition products of dichlorocarbene to alkenes being a part of pyrocondensate are formed
Authors and Affiliations
R. Z. Shahnazarli, K. G. Guliyev, N. Ya. Ishenko, A. M. Aliyeva, B. A. Mamedov, D. R. Nurullayeva, J. I. Fattayeva
Keywords
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