Synthesis of [Oxa-, Thia-diazoles- and Triazole]-Thiols Derived from Butyric Acid: Conductivity Property, Complex Formation with Fe (II), Hg (II), and Synthesis of Seco-Acyclo-S-Glycosides
Journal Title: Chemical Science International Journal - Year 2017, Vol 18, Issue 4
Abstract
Three heterocyclic thiols: 2- propyl-1.3.4 – oxadiazole-5-thione/thiol 4/7, 2- propyl-1.3.4 – thiazole-5-thiole 8, 3- propyl-1.2.4 – triazole-5-thiole 9 have been synthesized from butyric acid. They showed conductivity properties and complex formation with Fe (II) and Hg (II) ions. New S-seco-acyclo-glycosides namely: 2-propyl -1,3,4-oxadiazole-5-thionyl-(1,3-dioxanyl) glycoside 12, 2-propyl -1,3,4-thiadiazole-5-thionyl-(1,3-dioxanyl) glycoside 13 and 3-propyl -1,2,4-triazole-5-thionyl-(1,3-dioxanyl) glycoside14 were synthesized from 7,8,9. Synthesis of nucleobases-complexes with Fe+2 and Hg+2 ions 15-20were achieved. Characterization of synthesized compounds were done by IR and1H-NMR spectroscopy. Potential conductivity of synthesized complexes were determined.
Authors and Affiliations
Djilali Boulerba, Adil A. Othman, Mohamed B. Taouti
Keywords
Related Articles
- EP ID EP319648
- DOI 10.9734/CSIJ/2017/32468
- Views 86
- Downloads 0
Photochemical Study for Solar Energy Conversion & Storage in Solar Cell: Yellow 5GN-EDTA System
The photovoltages and photocurrent in photogalvanic cell were studied for conversion and storage of solar energy by using yellow 5GN as a photo sensitizer and EDTA as a reductant. The observed cell performance in terms o...
Novel Imidazole and Dibenzothiophene-dioxide Containing Tetracyclic Systems
The aim of the current work is synthesis of new heterocyclic teratacyclic condensed systems that combine dibenzothiophenedioxide and imidazole in one molecule. The dibenzothiophene was taken as an initial compound and by...
Concentration Levels and the Associated Health Risks of Elements in Food Crops Grown in the Neighbourhood of Minjingu Phosphate Mine, Tanzania
The concentration levels of heavy metals in food crops (maize and mung beans) grown in the neighbourhood of Minjingu Phosphate mine were analyzed using EDXRF. The metal concentrations in both food crops followed the foll...
Metabolites Detected in the Crude N-Hexane Extract of Artemisia annua Linn (Asteraceae) Cultivated in Langtang, Plateau State, Nigeria
Artemisia annua was grown in and harvested from Langtang, Plateau State in Nigeria. The dried pulverized aerial part of Artemisia annua was extracted with n-hexane by percolation and concentrated in vaccum at 40°C. Analy...
Chemical Fractionation of Heavy Metals in the Soil of Auto-Mechanic Workshops in Akure, Ondo State, Nigeria
Total metal concentrations and sequential extraction scheme were employed to investigate the potential environmental risk of seven important metals in the soil of selected auto-mechanic workshops in Akure metropolis, Ond...