The Green Synthesis of Chitosan Based Super Absorbent Polymerto Enhance Water Holding Capacity of Soil

Abstract

Super Absorbent Polymers (SAP) are cross-linked hydrophilic polymers having three-dimensional network, which absorb and retain huge quantities of water than their original mass and volume, and release during the dry conditions. Super absorbent polymers are used as soil conditioner in agriculture for improving soil water holding capacity. The conventional hydrogels available in the market are acrylate-based products, which are not biodegradable and hazardous in nature. This research was attempted to synthesize super absorbent polymers from renewable sources along with biocompatible cross linkers to make it completely biodegradable and biocompatible for agricultural use. In this current study, hydrogels were synthesized using chitosan cross-linked with polyethylene glycol, citric acid and oxalic acid. Chitosan based hydrogels were characterized for moisture content, equilibrium water absorbency, swelling ability in acidic (pH=4) and alkaline (pH=10) conditions. The surface morphology and cross-linking of hydrogel was characterized through electron microscopy and Fourier transform infrared spectroscopy respectively. The results showed that equilibrium water absorbency of chitosan cross-linked with polyethylene glycol was 3851 per cent of hydrogel followed by hydrogel with oxalic acid retained 3130 per cent. Similar trend of swelling capacity was observed in acidic and alkaline pH. Soil water holding capacity amended with hydrogels was determined through Keen-Rackzowski box, which revealed that soils amended with chitosan – graft- oxalic acid @ 0.1 per cent exhibited higher water holding capacity even after drying for 7h in oven at 70°C.

Authors and Affiliations

Gowtham Golla, Marimuthu S, Subramanian K. S, Santhanakrishnan V. P

Keywords

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  • EP ID EP649108
  • DOI 10.24247/ijasraug201915
  • Views 163
  • Downloads 0

How To Cite

Gowtham Golla, Marimuthu S, Subramanian K. S, Santhanakrishnan V. P (2019). The Green Synthesis of Chitosan Based Super Absorbent Polymerto Enhance Water Holding Capacity of Soil. International Journal of Agricultural Science and Research (IJASR), 9(4), 107-118. https://europub.co.uk/articles/-A-649108