THE HYDROSILYLATION OF 3-(HEXEN-5-IN-2-ILOXY) PROPIONITRILE
Journal Title: Azerbaijan Chemical Journal - Year 2018, Vol 0, Issue 1
Abstract
The addition reaction of triorganosilanes to 3-(hexen-5-in-2-iloxy) propionitryle in the presence of acetylacetonate dicarbonyl rhodium catalyst proceeds on triple bonds in two directions obtaining of β(52–65%)- and γ(35–48%)-isomers mixture (relatively oxygen atom) and with advantage of β-yield
Authors and Affiliations
A. M. Garamanov, M. Sh. Gurbanov, D. G. Abdullaev, N. Kh. Husiev, S. N. Allakhverdieva
Keywords
Related Articles
- EP ID EP469144
- DOI 10.32737/0005-2531-2018-1-59-64
- Views 129
- Downloads 0
OXIDATION OF HYDROGEN SULPHIDE WITH NITRIC ACID TILL SULPHUR AND IT REPRODUCTIVITY AT REACTION MEDIUM
Possibilities of oxidation of hydrogen sulphide with nitric acid till sulphur and at the same time repro-ductivity of nitric acid at reaction medium were studied. 100% oxidation of H2S to sulphur and full re-productivit...
PHASE DIAGRAMS IN DESIGN OF TOPOLOGICAL INSULATORS BASED ON COMPLEX THALLIUM CHALCOGENIDES
The topic of this review is to briefly present the chemistry of the topological insulators (TIs) based on thallium chalcogenides. Numerous phase diagrams of ternary Tl–BV–X (BV – Sb, Bi; X – Se, Te) systems include TlBVX...
LIQUID-PHASE OXIDATION OF CUMENE BY MOLECULAR OXYGEN IN THE PRESENCE OF N-(p-ACETAMIDPHENYL)IMIDE DICHLOROMALEIC ACID
Oxidation reaction of cumene with molecular oxygen at 1000С in the presence of N-(p-acetamidphenyl) imide di-chloromaleic acid synthesized has been investigated in vitro by the method developed by us. It is found that im...
SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM(V) IN THE CLAY SAMPLES
Complexation of vanadium(V) with a reagent synthesized based on pyrogallol – 2,3,4-trihydroxy-5-sulphoazonaphtalin has been studied by spectrophotometric method. It was found that at pH=5, λmax = 437 nm intensively colo...
REFINEMENT OF THE PHASE DIAGRAMS OF THE FeSe–Ga2Se3 AND Ga2Se3–In2Se3 SYSTEMS
The quasi-binary systems FeSe–Ga2Se3 and Ga2Se3–In2Se3 were reinvestigated by using DTA as well as RFA methods and their refined T–x phase diagrams were constructed. A comparative analysis of the results obtained with...