THE INVESTIGATION OF CONVERTION OF BENZYLIDENEMALONONITRILES WITH ACETOACETANILIDE

Journal Title: Azerbaijan Chemical Journal - Year 2018, Vol 0, Issue 4

Abstract

By the Michael addition reaction of p-methyl, p-nitro substituted benzylidenemalononitriles and thio-phe¬¬ny¬¬lidenemalononitrile with acetoacetanilide pyridine derivatives were synthesized. Michael addition re¬ac¬¬tion was carried out for 2,6-dichlorobenzylidenemalononitrile with acetoacetanilide and (E)-2-amino-4-(2,6-dichlorophenyl)-5-(1-hydroxyethylidene)-6-oxo-1-phe¬nyl-1,4,5,6-tetrahydropyridine-3-car¬bo¬¬nitrile that is corresponding derivative of pyridine was obtained. Unlike V, VI and VII in this reaction the main pro¬duct of this reaction is mainly in enol-form. Also the Michael addition reaction of p-trifluo¬ro¬ben¬zy¬li¬de¬ne¬malo¬no¬nit¬rile and 2-chloro-5-nitrobenzylidenemalononitrile with acetoacetanilide has been investigated

Authors and Affiliations

A. M. Maharramov, F. N. Naghiyev, A. R. Asgerova, E. Z. Guseynov, I. G. Mamedov

Keywords

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  • EP ID EP493358
  • DOI 10.32737/0005-2531-2018-4-33-38
  • Views 131
  • Downloads 0

How To Cite

A. M. Maharramov, F. N. Naghiyev, A. R. Asgerova, E. Z. Guseynov, I. G. Mamedov (2018). THE INVESTIGATION OF CONVERTION OF BENZYLIDENEMALONONITRILES WITH ACETOACETANILIDE. Azerbaijan Chemical Journal, 0(4), 33-38. https://europub.co.uk/articles/-A-493358