溶剂热合成手性三维开放式网络<br /> [Zn(pydc) (DMA)]n•2(DMA)<br />
Journal Title: Science Paper Online - Year 2008, Vol 3, Issue 6
Abstract
本文通过溶剂热方法合成一种具有手性孔道的三维开放骨架结构的配位聚合物[Zn(pydc) (DMA)]n•2(DMA)。单晶X射线衍射分析表明该化合物结晶于正交晶系,空间群P212121,晶胞参数a=1.0771(5) nm,b=1.1528(5) nm,c=1.4879(5) nm,α=β=γ= 90.00(0)°,V =1.8475(13) nm3。该化合物是由吡啶-3,5-二羧酸(pydc)配体桥连Zn离子构筑的三维网络。
Authors and Affiliations
Xinlong WANG , Chao QIN
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