DETERMINATION AND PRECONCENTRATION OF MANGANESE USING IONIC LIQUID BASED MICROEXTRACTION TECHNIQUE IN BIOLOGICAL SAMPLES
Journal Title: Academic Research International - Year 2013, Vol 4, Issue 4
Abstract
In this work, a procedure for preconcentration and determination of manganese using modified cold-induced aggregation microextraction(CIAME) based ionic liquid with the reagent 1-(2-pyridylazo)-2-naphthol (PAN) as complexing reagent was developed. In the preconcentration step, the mixture was cooled in an ice bath and manganese from 10mL of an aqueous solution was extracted into70µL of ionic liquid, 1-hexyl-3-methylimidazolium hexafluorophosphate [Hmim][PF6]. After centrifuging the extraction phase was settled. Then, the absorbance of the complex was measured by UV-Vis spectrophotometry. In this study, the effect of matrix ions on the extraction efficiency of Mn+2 were investigated. Also the optimization extractionconditions, such as: pH, PAN concentration, extraction time, addition of salt, ionic liquid volume and centrifugation rate were studied. The relative standard deviation was 1.14 % (n=4). The detection limit of 0.54 ngL-1 and enrichment factor of 70 for Mn+2 were achieved. The presented procedure was successfully applied for determination of manganese in environmental and biological samples.
Authors and Affiliations
Fariba Tadayon, Mahnoosh Hanasaei, Masoumeh Madadi
Keywords
Related Articles
- EP ID EP120408
- DOI -
- Views 119
- Downloads 0
Analysis of Works Ability and Entrepreneurial Spirit to Service Quality of Government Officials in Banda Aceh
Theaims of study are not only to agains over view of phenol men on that is supported by empirical evidencebut also to find clarity and conclusions about the relationship between work ability and entrepreneurial spirit fa...
EFFECT OF FERROUS SULPHATE ON THE SIMULTANEOUS ORGANIC MATTER AND NUTRIENT REMOVAL PERFORMANCE OF SEQUENCING BATCH REACTOR
The aim of this study was to evaluate the effect of ferrous sulphate on the simultaneous organic matter and nutrient removal performance of sequencing batch reactor (SBR). Two reactors, namely a SBR1 (with FeSO4.7H2O dos...
THE SHADOWED IDENTITY: A STUDY OF ALICE WALKER’S THE COLOR PURPLE
The term Afro-American as a literary genre started to be considered from the so-called Harlem Renaissance at the beginning of the twentieth century; in fact, Harlem Renaissance can be considered as the spring o...
IS IT THE WAY TO TEACH LANGUAGE THE WAY WE TEACH LANGUAGE? ENGLISH LANGUAGE TEACHING IN RURAL PAKISTAN
With the growing importance and need of English language in the global context, efforts are being made in the developing context to improve the quality of teaching English with the assumption that teaching of English...
Relationship between Continuance Commitment and Turnover Intention among Healthcare Internal Auditors in the US
Investigating factors that drive employee turnover has attracted the attention of both scholars and practitioners in the past few decades. The purpose of this study was to add to the body of knowledge on drivers of empl...