Development of a rheological model for polymeric fluids based on FENE model

Journal Title: Polyolefins Journal - Year 2019, Vol 6, Issue 1

Abstract

Rheological models for polymer solutions and melts based on the fnitely extensible non-linear elastic (FENE) dumbbell theory are reviewed in this study. The FENE-P model that is a well-known Peterlin approximation of the FENE model, indicates noticeable deviation from original FENE predictions and also experimental results, especially in the transient flow. In addition, both FENE and FENE-P models have some shortcomings from the point of view of theory. To overcome these shortcomings, a new approximation of the FENE spring force has been established. It has been used to develop a modifed constitutive rheological model for polymeric fluids. In the procedure of modeling, the effect of non-affne deformation is introduced into the new model. Comparison between the model predictions and experimental data presented in the literature for transient and steady shear flow of polystyrene indicates that this modifed model can predict the rheological behavior of polymeric fluids with a great accuracy. The newly developed modifed model could predict different slopes that can cover the behavior of most of the polymeric fluids.

Authors and Affiliations

Hossein Ebrahimi, Ahmad Ramazani S. A. , Seyed Mohammad Davachi

Keywords

Related Articles

Estimation of pyrolysis product of LDPE degradation using different process parameters in a stirred reactor

Pyrolysis of low density polyethylene (LDPE) by equilibrium fluid catalytic cracking (FCC) was studied in a stirred reactor under different process parameters. In this work, the effect of process parameters such as degra...

Oxygen-barrier films based on low-density polyethylene/ ethylene vinyl alcohol/ polyethylene-grafted maleic anhydride compatibilizer

In this research, high oxygen-barrier films were organized based on low-density polyethylene (LDPE)/ ethylene vinyl alcohol (EVOH)/ polyethylene-grafted maleic anhydride (LDPE-g-MA) compatibilizer. The effects of 10–30 w...

Tuning the short chain branch distribution of ethylene and 1-hexene copolymers by SiO2-supported silyl chromate catalyst with different Al-alkyl co-catalysts

SiO2-supported silyl chromate catalyst is an important industrial catalyst for production of high grade HDPE pipe materials. The control of the short chain branch (SCB) distribution using this catalyst system is still a...

Effect of temperature, heating rate and zeolite-based catalysts on the pyrolysis of high impact polystyrene (HIPS) waste to produce fuel-like products

Pyrolysis of high impact polystyrene (HIPS) waste has been investigated under different process parameters, such as temperature, heating rate and types of zeolitic catalysts to produce valuable liquid products. Liquid, g...

Phillips catalysts synthesized over various silica supports: Characterization and their catalytic evaluation in ethylene polymerization

Ethylene polymerization was carried out using Phillips chromium catalyst based on silica supports such as silica aerogel, SiO2 (Grace 643), and titanium modified SiO2 (G 643), and the results were compared with other cat...

Download PDF file
  • EP ID EP438566
  • DOI 10.22063/poj.2018.2318.1125
  • Views 110
  • Downloads 0

How To Cite

Hossein Ebrahimi, Ahmad Ramazani S. A. , Seyed Mohammad Davachi (2019). Development of a rheological model for polymeric fluids based on FENE model. Polyolefins Journal, 6(1), 95-106. https://europub.co.uk/articles/-A-438566