Haloacetic acids species from the chlorination of algal organic matter in the presence of bromide
Journal Title: Science Paper Online - Year 2011, Vol 6, Issue 12
Abstract
Bromide and algal pollution are important factors influencing disinfection byproducts (DBPs) formation and speciation in reservoir water in coastal areas. The chlorination of model algal cellular compounds (bovine serum albumin, fish oil and starch), Microcystis aeruginosa and its extra-cellular organic matters (EOMs) were conducted in the absence and presence of bromide. The main aim of the present study is to explore their potential as precursors for haloacetic acids (HAAs) speciation upon chlorination in the presence of bromide. The results showed that bromochloroacetic acid (BCAA) or/and dibromoacetic acid (DBAA) was/were produced as for brominated HAAs (Br-HAAs) from the three model compounds in the presence of bromide. The effect of bromide on Br-HAAs speciation upon fish oil chlorination was more evident than with BSA and starch. There was a good correlation between the species predicted from the model compounds and those obtained from specific algal species.
Authors and Affiliations
Yuanyuan Wei, Yan Liu, Xiang Liu, Ruihua Dai
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