PRODUCT OF THE INTERACTION OF TIN TETRACHLORIDEHYDRAZIDE COMPLEXES WITH AROMATIC ALDEHYDES
Journal Title: Вісник Одеського національного університету. Хімія - Year 2014, Vol 19, Issue 1
Abstract
The principle possibility of obtaining condensation products R-benzoic aldehyde (R = H, 4-N(CH3)2, 2-OH) and zwitterionic complexes of SnCl4with hydrazides 2- and 4- aminoben-zoic acids. It is proved (IR, mass spectrometry, thermal gravimetric analysis, conductivity), that in the complexes that are formed, аlso implemented enol form of the ligand (hydra- аlso implemented enol form of the ligand (hydra- lso implemented enol form of the ligand (hydra-zone). In the case of bidentate coordination (R = H, 4-N(CH3)2) remains the coordinating node {SnCl4ON}-, which is characteristic for hydrazide complexes and when tridentate (R = 2-OH) – it varies {SnCl3O2N}-.
Authors and Affiliations
N. V. Shmatkova, I. I. Seifullina
Keywords
Related Articles
- EP ID EP408005
- DOI 10.18524/2304-0947.2014.1(49).38328
- Views 79
- Downloads 0
SYNTHESIS, FTIR SPECTROSCOPY, AND SURFACE MICROMORPHOLOGY OF Се(III) AND Ce(IV)-CONTAINING HETEROPOLY TUNGSTATES WITH PEACOCK–WEAKLEY STRUCTURE OF ANION
The conditions for the synthesis of sodium heteropoly decatungstoceriate(III) Na9[CeIII(W5O18)2]·28H2O from the aqueous solution of sodium tungstate acidified to Z=ν(H+)/ν(WO42–)=0.80 with a ratio ν(Ce):ν(W)=1:10 and wit...
SYNTHESIS OF METALLOCOMPLEXES OF WATER SOLUBLE BISQUINOLINYLPORHYRINS AS POTENTIAL ANTIMICROBIAL AGENTS
At present, extensive research is being carried out on the phenomenon of resistance of microbes to antibiotics, including the newest of them. Among the most promising drug candidates for treatment such superbugs is deriv...
SYNTHESIS AND DNA AFFINITY OF 1-DIALKYLAMINO-3- INDOLO [2,3-b] QUINOXALINE-6-YLPROPAN-2-OLS
DNA intercalators demonstrated a broad spectrum of terapeutic activities, such as anticancerogenic, antimicrobic and antiviral as well as ciototoxic, mutagenic and embriotoxic. One of the main marks of DNA-drug interacti...
STRATEGY AND PREPARATION OF SOME BUILDING BLOCKS FOR SYNTHESIS OF BRANCHED OLIGOSACCHARIDES
The importance of the role of oligosaccharides in biological processes relating to immunology, virology, cancer, antibiotic action has heightened the interest in accessibility and study of methods of their synthesis, inc...
GETERONUCLEAR BIS(GALACTARATO)GERMINATES OF COBALT(ІІ), COPPER(ІІ), NICKEL(ІІ): SYNTHESIS, STRUCTURE AND CHEMICOPHYSICAL PROPERTIES
Heterometallic bic(galactarato)germanates of cobalt(ІІ), copper(ІІ) and nickel(ІІ) were synthesized for the first time and characterized with the method of elemental analyses, thermogravimetry and IR-spectroscopy. The IR...