TRANSFORMATIONS OF BENZO-15-CROWN-5, [3.3]DIBENZO-18-CROWN-6 AND [4.4]DIBENZO-24-CROWN-8 IN AQUEOUS SOLUTIONS OF NITRIC ACID
Journal Title: Вісник Одеського національного університету. Хімія - Year 2014, Vol 19, Issue 1
Abstract
Peculiarities of benzo-15-crown-5 (I), [3.3]dibenzo-18-crown-6 (II), and [4.4]diben zo-24-crown-8 (III) nitration by the dilute nitric acid and the mixture HCl-HNO3(4:1, «aqua regia») at room temperature are discussed. It was revealed that the «reactivity» of studied crown ethers (symbatically/antisymbatic to their hydrophili ci ty/lipophilicity) is variated as follows: I>> III> II.
Authors and Affiliations
S. M. Pluzhnik-Gladyr
Keywords
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- EP ID EP407995
- DOI 10.18524/2304-0947.2014.1(49).38309
- Views 68
- Downloads 0
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