Regioselective and facile oxidative thiocyanation of anilines and indoles with trans-3,5?dihydroperoxy-3,5?dimethyl?1,2?dioxolane
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 10, Issue 8
Abstract
Oxidative potential of trans3,5dihydroperoxy3,5dimethyl1,2dioxolane (DHPODMDO) has been explored in the facile thiocyanation of anilines and indoles through the efficient and in situ generation of SCN+ ion from sodium thiocyanate. The reactions proceed with regioselectivity under mild conditions at room temperature to afford the respective thiocyanate derivatives in excellent yields and low reaction times.
Authors and Affiliations
Davood Azarifar, Maryam Golbaghi, Mahtab Pirveisian, Zohreh Najminejad
Keywords
Related Articles
- EP ID EP652803
- DOI 10.24297/jac.v10i8.2247
- Views 125
- Downloads 0
Concentration of Heavy Metals in the Soils near Some Mechanic Villages in Abeokuta Metropolis, Ogun State, Nigeria.
Soils and water bodies near auto mechanic village (MV) contain heavy metals, which pollute the environments and are hazardous to human and environmental health. Assessment of heavy metal concentration in three replicate...
D/L arabinitol Ratio as an Indicator of a Healthy Lifestyle. A preliminary Study
D-arabinitol, as opposed to the L-arabinitol, is produced by fungi of the genus Candida. The increasedD/L-arabinitol ratio in body fluids is a recognized biomarker of systemic fungal infection . The factors which increas...
Performances of nanofiltration on industrial phosphoric acid purification
Phosphoric acid production is of major importance to the Tunisian economy. However, the quality produced is not suitable for other than agricultural use due to mineral and organic impurities. In this study, the purificat...
Mathematical model of vacuum freeze-drying in the secondary drying
The freeze-drying process is a complex heat and mass transfer process virtually. The drying process of freeze-drying is not only the key stage which decides the success of freeze-drying, but also the most difficult stage...
Convenient Synthesis of Some New Bi-heterocycles conataining 3-Aminoquinazolin-4(3H)-one and 1,2,4-Triazole moieties
Dicarboxylic acids, thiosemicarbazides and methylanthranilate reacted to give methyl-2-(3-(5-mercapto-4-s-1,2,4-triazol-3-yl)-3-oxoalkylamino)benzoates 4. The laters, cyclized with hydrazine hydrate to give 3-amino-2-((5...