Regioselective and facile oxidative thiocyanation of anilines and indoles with trans-3,5?dihydroperoxy-3,5?dimethyl?1,2?dioxolane
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 10, Issue 8
Abstract
Oxidative potential of trans3,5dihydroperoxy3,5dimethyl1,2dioxolane (DHPODMDO) has been explored in the facile thiocyanation of anilines and indoles through the efficient and in situ generation of SCN+ ion from sodium thiocyanate. The reactions proceed with regioselectivity under mild conditions at room temperature to afford the respective thiocyanate derivatives in excellent yields and low reaction times.
Authors and Affiliations
Davood Azarifar, Maryam Golbaghi, Mahtab Pirveisian, Zohreh Najminejad
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