SbCl3-Catalyzed conversion of ketones and aldehydes into gem-dihydroperoxides (DHPs) with 30% H2O2

Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2015, Vol 11, Issue 5

Abstract

A simple and efficient conversion of ketones and aldehydes into corresponding gem-dihydroperoxides (DHPs) has been developed by SbCl3-catalyzed oxidation with 30% H2O2 at room temperature. The reactions proceeded smoothly under mild conditions at room temperature. Simple experimental procedure, use of inexpensive and non-toxic catalyst, high yields and low reaction times are the main merits of the present method.

Authors and Affiliations

Davood Azarifar, Boshra Mahmoudi, Kaveh Khosravi

Keywords

Related Articles

A new Rubidium - Bismuth polyphosphate RbBi(PO3)4: Growth, X-ray single crystal and vibrational study

Solid-solution studies in the ternary Rb2O – Bi2O3 – P2O5 system, carried out in a search for inorganic materials have a considerable interest mainly for their optical properties, specifically in laser technology, yi...

Studies on lipase enzyme production by indigenously isolated Bacillus Cereus (BAIT GCT 127002 ) and Bacillus Cereus (BAIT GCT 127001)

Microbial lipases holds a prominent place among biocatalysts that act on carboxylic ester bonds.  This present study involves about eight strains isolated form slaughter house waste water,Coimbatore producing lipas...

Computational Study of the Stability of Tautomers and equilibrium constants of Cyanuric acid (CA) in Different solvents.

In the present investigation, the tautomeric and equilibrium of Cyanuric acid has been studied using Hartifock (HF) method in the gas phase and different solvents using the PCM model. The relative energies of these tauto...

Acid Attack On Hybrid Fiber Reinforced High Strength Concrete With Manufactured Sand and Coconut Shell

In this study, the acid attack test is performed on the fiber reinforced concrete incorporating with manufactured sand silica fume and coconut shell. The grade of concrete is M50. Silica fume is partially replaced with 1...

Removal of Carcinogenic Hexavalent Chromium by Reduction with Iron in Presence of Accelerator Non Toxic Organic Compounds (Chalcone)

The focus of this work is on Cr, which has two predominant oxidation states of the atmosphere: + ‏3, which is an essential nutrient in low doses, and +‏6, which is highly toxic and carcinogenic. We found that, the re...

Download PDF file
  • EP ID EP652854
  • DOI 10.24297/jac.v11i5.4473
  • Views 107
  • Downloads 0

How To Cite

Davood Azarifar, Boshra Mahmoudi, Kaveh Khosravi (2015). SbCl3-Catalyzed conversion of ketones and aldehydes into gem-dihydroperoxides (DHPs) with 30% H2O2. JOURNAL OF ADVANCES IN CHEMISTRY, 11(5), 3547-3553. https://europub.co.uk/articles/-A-652854