半透膜被动采样装置(SPMD)对水中<br /> 典型酚类内分泌干扰物的富集研究<br />

Journal Title: Science Paper Online - Year 2009, Vol 4, Issue 5

Abstract

对3种典型酚类内分泌干扰物——双酚A(BPA)、辛基酚(OP)和壬基酚(NP)由水相到半透膜被动采样装置(SPMD)的富集动力学进行了实验室研究。研究发现,SPMD对OP和NP具有较好的富集效果,而对于BPA的富集能力较低。在4 ℃条件下,20 d内3种物质在水相和SPMD相间未达到分配平衡,而在15和25 ℃时,OP和NP可分别在3~15 d内达到分配平衡。将目标化合物的SPMD和水相分配平衡常数KSPMD实测值与经验计算值进行比较表明,二者之间存在较大偏差。改变水溶液pH值、碱度和硬度条件,观察其对目标化合物在SPMD相中的一日富集质量浓度ρs,1 d的影响。结果表明,在高pH值条件下,酚类目标污染物的离子化可导致其ρs,1 d的降低,而溶液碱度和硬度则对富集速率无显著影响。

Authors and Affiliations

Teng Tu, Hongyu Wang, Jiaxing Li

Keywords

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  • EP ID EP123858
  • DOI -
  • Views 141
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How To Cite

Teng Tu, Hongyu Wang, Jiaxing Li (2009). 半透膜被动采样装置(SPMD)对水中<br /> 典型酚类内分泌干扰物的富集研究<br /> . Science Paper Online, 4(5), 319-323. https://europub.co.uk/articles/-A-123858