Structural and electron aspects of nitrogen–nitrogen bond
Journal Title: CHEMIK nauka-technika-rynek - Year 2014, Vol 68, Issue 4
Abstract
Nitrogen, like many other chemical elements, has catenation ability. The largest family of compounds containing Nx systems are compounds containing two nitrogen atoms, and the most numerous among them are hydrazo, azo, azoxy, azodioxy compounds and compounds with nitramine group. In the presented studies for determining changes in nitrogennitrogen bond length, average lengths were calculated based on quantum mechanical calculations and data from crystallographic database CSD. Furthermore, the aromaticity of phenyl rings connected to studied functional groups was calculated using HOMA aromaticity index based on geometric criteria.
Authors and Affiliations
K. Gajda, B. Zarychta
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