Study on the performance and mechanism of high-efficiency deep oxidation of butyl acetate over Pd/CeO_2
Journal Title: Energy Environmental Protection - Year 2024, Vol 38, Issue 4
Abstract
In the field of new energy vehicles and related sectors, treating butyl acetate (BA), a typical oxygen-containing volatile organic compound (VOC), is becoming increasingly important. The surface structure and physicochemical properties of a CeO_2-U catalyst were adjusted by introducing 0.5% Pd, and compared with Al_2O_3 and TiO_2 catalysts containing the same Pd loading. Characterizations using SEM, XPS, in-situ DRIFTS, and other methods were conducted to explore the synergistic effect of Pd and Ce active components on catalytic oxidation of BA. The results showed that the introduction of Pd increased CeO_2-U′s CO_2 yield from 77.8% to 90.7% at 220 ℃, significantly promoting the deep oxidation process of BA and alleviating the issue of CO_2 selectivity delay. The introduction of Pd enhanced the mobility and reactivity of lattice oxygen in CeO_2, increased the proportion of surface Ce^3+, and boosted surface oxygen vacancy concentration. Additionally, the catalytic oxidation mechanism of BA over Pd/CeO_2-U was confirmed through in-situ DRIFTS analysis, indicating that the L-H mechanism was followed at low temperatures (T<200 ℃), while the MvK reaction mechaism occured followed at high temperature (T>200 ℃). It was found that the decomposition of intermediate carboxylate served as the rate-controlling step. These findings have implications for controlling BA in the field of related sectors.
Authors and Affiliations
KONG Wenjing|College of Environment and Energy, South China University of Technology, Guangzhou 510006, China, LIN Jiajia|College of Environment and Energy, South China University of Technology, Guangzhou 510006, China, ZHONG Xueyun|College of Environment and Energy, South China University of Technology, Guangzhou 510006, China, XING Yun|College of Environment and Energy, South China University of Technology, Guangzhou 510006, China, LIU Peng|College of Environment and Energy, South China University of Technology, Guangzhou 510006, China, Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou 510006, China, LI Zhenguo|National Engineering Laboratory for Mobile Source Emission Control Technology, China Automotive Technology & Research Center Co., Ltd., Tianjin 300300, China, FU Mingli*|College of Environment and Energy, South China University of Technology, Guangzhou 510006, China, Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou 510006, China
Keywords
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- EP ID EP743143
- DOI 10.20078/j.eep.20240710
- Views 30
- Downloads 0
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