Synthesis and Crystal Structure of 3-3'-Diaminomethyldipropylammonium Hexachlorobismuthate (III)
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 8, Issue 1
Abstract
Synthesis and crystal structure of 3-3-diamino-N-methyldipropylammonuim hexachlorobismuthate (III) are reported. The compound crystallizes in the triclinic system with space group P1. The unit cell dimensions are: a = 7.5580(5), b =7.8710(6), c = 8.3709(7)… with Z=1. The crystal is built up of separated [BiCl6]3- octahedral anions and 3-3-diamino-N- methyldipropylammonium cations. The organic layers are arranged in sandwich between the anionic ones. The crystal packing is governed by means of the ionic N“HCl hydrogen bonds, forming a three dimensional network.
Authors and Affiliations
Yosra Baklouti, Abdelaziz Koumina, Mohamed Fliyou, Fatma Zouari
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