Synthesis and Crystal Structure of 3-3'-Diaminomethyldipropylammonium Hexachlorobismuthate (III)

Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 8, Issue 1

Abstract

Synthesis and crystal structure of 3-3-diamino-N-methyldipropylammonuim hexachlorobismuthate (III) are reported. The compound crystallizes in the triclinic system with space group P1. The unit cell dimensions are: a = 7.5580(5), b =7.8710(6), c = 8.3709(7)… with Z=1. The crystal is built up of separated [BiCl6]3- octahedral anions and 3-3-diamino-N- methyldipropylammonium cations. The organic layers are arranged in sandwich between the anionic ones. The crystal packing is governed by means of the ionic N“HCl hydrogen bonds, forming a three dimensional network.

Authors and Affiliations

Yosra Baklouti, Abdelaziz Koumina, Mohamed Fliyou, Fatma Zouari

Keywords

Related Articles

Synthesis, Characterization and biological evaluation of Novel Carboxamides, Oxadiazoles and Isoindoline-1,3-diones derived from 2-substituted phenylquinoline-4-carbohydrazides.

The new 2-arylquinoline-4-carboxylic acid derivatives 4(a-f) and 5(a-i), were tested by qualitative and quantitative methods on various bacterial and fungal strains and proved to be active at low concentrations against G...

INVESTIGATION IMIDAZOLINE DERIVATIVES OBTAINED FROM SYNTHETIC PETROLEUM ACIDS AS CORROSION INHIBITOR

Imidazoline derivatives have been synthesized based on the synthetic petroleum acids (SPA) and diethylentriamine. Complexes were prepared from these compounds and HCl in ratio 1:1, 1:2, 1:3. 20% solution of the complexes...

Spectroscopic Study of some Schiff Bases Derived from Dibenzoylmethane

A series of Schiff bases 7-11 derived from dibenzoylmethane have been prepared. The UV, IR, 1H NMR and mass spectra revealed theses compounds were existed mainly as the keto-enamine tautomer in the solution. The absorpti...

Preparation, Surface active properties, and Anticorrosion Application of some novel surfactants based on cottonseed oil and diethanolamine on carbon steel in CO2 environments

Novel surfactants were synthesized based on cottonseed oil and diethanolamine and the structures of these compounds were confirmed by FTIR spectroscopy. The surface and thermodynamic properties of these compounds have be...

DEVELOPMENT AND COMPARISON OF ORALLY INHALABLE SUSTAINED RELEASE FORMULATIONS FOR THREE RESPIRATORY DRUGS FOR ASTHMA

The present work was designed to develop and compare orally inhalable sustained release formulation for salbutamol sulphate (SS), ambroxol hydrochloride (AH) and montelukast sodium (MS).The emulsion solvent evaporation m...

Download PDF file
  • EP ID EP652657
  • DOI 10.24297/jac.v8i1.4031
  • Views 160
  • Downloads 0

How To Cite

Yosra Baklouti, Abdelaziz Koumina, Mohamed Fliyou, Fatma Zouari (2014). Synthesis and Crystal Structure of 3-3'-Diaminomethyldipropylammonium Hexachlorobismuthate (III). JOURNAL OF ADVANCES IN CHEMISTRY, 8(1), 1500-1507. https://europub.co.uk/articles/-A-652657