Synthesis and Spectroscopic Properties of 5-Amino-1,3,4-Thiadiazole Substituted Zinc(II) Phthalocyanine Compound
Journal Title: Cumhuriyet Science journal - Year 2018, Vol 39, Issue 4
Abstract
Thiadiazole substituted phthalonitrile 1 was prepared by a nucleophilic displacement reaction of 4-nitrophthalonitrile with 5-Amino-1,3,4-thiadiazole-2-thiole. Thiadiazole tetrasubstituted zinc(II) monophthalocyanine 2 was synthesized by tetramerization of compound 1. The new compounds were characterized by 1H-NMR, UV-vis and IR spectra. Aggregation behavior of compound 2 was investigated both in different solvents (CHCl3, DMF, DMSO) and in different concentrations. The fluorescence properties of compound 2 were also studied.
Authors and Affiliations
Ebru YABAŞ
Keywords
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- DOI 10.17776/csj.457964
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