Synthesis, Crystal Structure, and Characterization of the first Organic Cation Hexaoxoperiodate
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 9, Issue 1
Abstract
The title compound is an organic-inorganic hybrid material. The single crystal X-ray diffraction investigation reveals that the studied compound crystallizes in the monoclinic system, space group P21/c with the following lattice parameters:               𑎠= 7.551 (2) Ã…, ð‘ = 6.694 (3) Ã…, ð‘ = 14.783 (2) Ã…, β = 97.61 (2)° and ð‘ = 2. The crystal lattice is composed of a discrete (H4IO6)− anion surrounded by piperazinium cations and water molecules. Complex hydrogen bonding interactions between the different chemical spices form a three-dimensional network. Room temperature IR, 13C NMR spectroscopy, thermogravimetric analysis and optical absorption of the title compound were recorded and analyzed.Â
Authors and Affiliations
I. Wacharine, Wajda Sta Smirani, M. Rzaigui
Keywords
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- EP ID EP652655
- DOI 10.24297/jac.v9i1.2301
- Views 161
- Downloads 0
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