X-ray Structure Refinement and Vibrational Spectroscopy of Ca8Gd2 (PO4)6 O2
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2013, Vol 5, Issue 2
Abstract
The present paper is interested in the study of compounds from the apatite family with the general formula Ca10 (PO4)6A2. It particularly brings to light the exploitation of the distinctive stereochemistries of two Ca positions in apatite. In fact, Gd-Bearing oxyapatiteCa8 Gd2 (PO4)6O2 has been synthesized by solid state reaction and characterized by X-ray powder diffraction. The site occupancies of substituents is0.3333 in Gd and 0.3333 for Ca in the Ca(1) position and 0. 5 for Gd in the Ca (2) position. Â Besides, the observed frequencies in the Raman and infrared spectra were explained and discussed on the basis of unit-cell group analyses.
Authors and Affiliations
R. Ayadi, Mohamed Boujelbene, T. Mhiri
Keywords
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- EP ID EP652599
- DOI 10.24297/jac.v5i2.2661
- Views 154
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