Addition of a second alcohol in magnesium ethoxide synthesis as a way to vary the pore architecture of Ziegler-Natta catalysts
Journal Title: Polyolefins Journal - Year 2015, Vol 2, Issue 2
Abstract
In Ziegler-Natta olefin polymerization, the pore architecture of catalysts plays a crucial role in catalytic performances and polymer properties. While the type of preparation routes (such as chemical reaction and solution precipitation) greatly affects the catalyst pore architecture as a result of different solidification mechanisms, the modification of the pore architecture within a given route has been hardly achieved. In this study, we propose a simple way to vary the pore architecture of Mg(OEt)2-based Ziegler-Natta catalysts by the addition of a second alcohol. It was found that the addition of a second alcohol during Mg(OEt)2 synthesis affected not only the morphology of Mg(OEt)2 macroparticles but also the shape of building units. The degree of alternation was found to be sensitive to the molecular structure of a second alcohol. Noticeable influences were observed in the case of branched alcohols, where the transformation of plate-like building units to cylindrical ones led to the generation of totally different pore size distributions of resultant catalysts.
Authors and Affiliations
Toshiaki Funako, Patchanee Chammingkwan, Minoru Terano
Keywords
Related Articles
- EP ID EP283120
- DOI 10.22063/POJ.2015.1131
- Views 101
- Downloads 0
Synthesis of high molecular weight polyethylene using FI catalyst
A FI Zr-based catalyst of bis[N-(3,5-dicumylsalicylidene)-2′,6′diisopropylanilinato]zirconium(IV) dichloride was prepared and used for polymerization of ethylene. The effects of reaction conditions on the polymerization...
Polymerization of propylene in a minireactor: Effect of polymerization conditions on particle morphology
Gas phase polymerization of propylene was carried out in a semi-batch minireactor using a commercially supported Ziegler–Natta (ZN) catalyst. The influence of variables including monomer partial pressure, external electr...
Intelligent catalysts for ethylene oligomerization and polymerization
Ethylene polymerization catalysts became available in an enormous variety. The challenge in this research is to find catalysts that are able to connect ethylene molecules in such a way that not only linear chains are pro...
Oxygen-barrier films based on low-density polyethylene/ ethylene vinyl alcohol/ polyethylene-grafted maleic anhydride compatibilizer
In this research, high oxygen-barrier films were organized based on low-density polyethylene (LDPE)/ ethylene vinyl alcohol (EVOH)/ polyethylene-grafted maleic anhydride (LDPE-g-MA) compatibilizer. The effects of 10–30 w...
Influence of branching on the rheology and morphology of melt state long-chain branched polypropylene/polybuten-1 blends
In this study, the compatibility of polypropylene (PP)/polybutene-1 (PB-1) homopolymer blends before and after a long-chain branching process was studied. The blends were prepared and long-chain branched directly via a r...