Emerging Trends in Coordination Polymers and Metal-Organic Frameworks: Perspectives, Synthesis, Properties and Applications
Journal Title: Archives of Organic and Inorganic Chemical Sciences - Year 2018, Vol 1, Issue 2
Abstract
Coordination polymers including metal-organic frameworks, clathrates and cyanometallates have recently gained significance as an important class of solid state materials. In this critical review, the diversity, classification, synthesis, structure, properties, applications, geometrical and chemical factors that influence their formation have been carefully presented. The synthesis of these new classes of compounds from molecular building blocks and demonstration oftheir high surface area, adsorptive and trapping potentials of molecules, selectivity in separation and uptake of molecules, tunable and modifiable molecular structure, and photoluminescence, magnetic and antimicrobial responses holds the potential for innumerable applications based on these tailored properties.The development of polymer materials with coordination complexes as repeating units has increased in recent years .In the past decade, there have been rapid growth in coordination polymers and this defines one of the most exciting fields in solid state chemistry. The surprising variety of structures, compositions and properties of these polymers as well as their easy modification and synthesis has attracted many researchers [1]. As a consequence of the various synthetic procedures followed with modifications of the structures of these polymers.
Authors and Affiliations
Nworie Felix Sunday
Advanced Oxidation Processes (AOPs) by Bismuth Oxyhalides for Environmental Remediation Using Solar Energy: Enhancing Material Property through Synthesis
To combat air and water pollution with green chemistry is one of the major issues. Several research groups, worldwide, are today engaged in the design and development of new photocatalytic materials which can act to make...
Kinetic Isotherm Studies of Azo Dyes by Metallic Oxide Nanoparticles Adsorbent
We reported the synthesis of Cu4O3 nanoparticles fabricated by Camellia Sinensis (green tea) leaves extract as reducing and stabilizing agent and studied the azo dyes removal efficiency. The formation of copper oxide nan...
Straw Based Biorefinery
n India energy security and exploring the production of valuable chemicals , which are otherwise mostly imported have become imperative necessity The advantage of abundant availability of paddy and its straws, specifical...
Heterobimetallic Aryloxides of Titanatranes with Aluminum Alkyls for Ring opening polymerization (ROP) of rac-Lactide
Olefin polymerization catalysis [1a-1b] continues to be an area of considerable importance to both the academic and industrial communities, and a wide range of reports are appearing on the efficient...
A Review of Organotin Compounds: Chemistry and Applications
The field of organotin chemistry has a long history that started since 1849, when Frankland isolated a specimen of diethyltin diiodide [1]. In 1852, Lowich reported on the reaction of alkyl halides with a tin-sodium allo...